Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis/Cyclic voltammetry in various conditions: Difference between revisions

From ChemWiki
No edit summary
No edit summary
Line 1: Line 1:
{{Cyclic Voltammetry experiments
{{Cyclic Voltammetry experiments
|experiments={{Cyclic Voltammetry
|experiments={{Cyclic Voltammetry
|anl=Molecule:100670
|anl=Molecule:100784
|anl conc=0.5
|anl conc=0.5
|solv=Molecule:100530
|solv=Molecule:100530
Line 14: Line 14:
|include=Yes
|include=Yes
}}{{Cyclic Voltammetry
}}{{Cyclic Voltammetry
|anl=Molecule:100670
|anl=Molecule:100784
|anl conc=0.5
|anl conc=0.5
|solv=Molecule:100530
|solv=Molecule:100530
Line 28: Line 28:
|include=Yes
|include=Yes
}}{{Cyclic Voltammetry
}}{{Cyclic Voltammetry
|anl=Molecule:100670
|anl=Molecule:100784
|anl conc=0.5
|anl conc=0.5
|solv=Molecule:100530
|solv=Molecule:100530
Line 42: Line 42:
|include=Yes
|include=Yes
}}{{Cyclic Voltammetry
}}{{Cyclic Voltammetry
|anl=Molecule:100670
|anl=Molecule:100784
|anl conc=0.5
|anl conc=0.5
|solv=Molecule:100530
|solv=Molecule:100530
Line 56: Line 56:
|include=Yes
|include=Yes
}}{{Cyclic Voltammetry
}}{{Cyclic Voltammetry
|anl=Molecule:100670
|anl=Molecule:100784
|anl conc=0.5
|anl conc=0.5
|solv=Molecule:100530
|solv=Molecule:100530

Revision as of 16:36, 1 August 2023

analyte anl conc [mM] reduction potential oxidation potential solvent solvent vol [ml] electrolyte electrolyte purity el conc [M] int ref comp scan rate [mv s-1] scan number potential window scan dir gas T [° C] condition [nm] WE WE surface area [mm²] CE RE Details include

[Ir(ppy)2(bpy)][PF6]

0.5

MeCN

TBA(PF6)

0.1


100 argon glassy carbon 7.07 platinum SCE Yes

[Ir(ppy)2(bpy)][PF6]

0.5

MeCN

TBA(PF6)

0.1


100 CO dark glassy carbon 7.07 platinum SCE Yes

[Ir(ppy)2(bpy)][PF6]

0.5

MeCN

TBA(PF6)

0.1


100 CO 420, 60 min glassy carbon 7.07 platinum SCE Yes

[Ir(ppy)2(bpy)][PF6]

0.5

MeCN

TBA(PF6)

0.1


100 CO 420, 1 min glassy carbon 7.07 platinum SCE Yes

[Ir(ppy)2(bpy)][PF6]

0.5

MeCN

TBA(PF6)

0.1


100 CO 420, 60 min glassy carbon 7.07 platinum SCE Yes