Photocatalytic CO2 reduction using a Mn complex as a catalyst/Photocatalytic CO2 reduction: conditions optimization: Difference between revisions
From ChemWiki
< Photocatalytic CO2 reduction using a Mn complex as a catalyst
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
No edit summary |
m (auto-generated) |
||
| Line 3: | Line 3: | ||
|catalyst=Molecule:100752 | |catalyst=Molecule:100752 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 18: | Line 18: | ||
|catalyst=Molecule:100752 | |catalyst=Molecule:100752 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 34: | Line 34: | ||
|catalyst=Molecule:100752 | |catalyst=Molecule:100752 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 50: | Line 50: | ||
|catalyst=Molecule:100752 | |catalyst=Molecule:100752 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 65: | Line 65: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 79: | Line 79: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 108: | Line 108: | ||
|catalyst=Molecule:100752 | |catalyst=Molecule:100752 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 122: | Line 122: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 138: | Line 138: | ||
|catalyst=Molecule:100752 | |catalyst=Molecule:100752 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
| Line 152: | Line 152: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|PS=Molecule: | |PS=Molecule:100659 | ||
|PS conc=0.05 | |PS conc=0.05 | ||
|e-D=Molecule:100509 | |e-D=Molecule:100509 | ||
Revision as of 16:01, 10 January 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 0.17 | 2 | 4 | 33.3%; 0%; 0%; 66.7%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 2 | 8 | 1 | 67 | 10.5%; 0%; 1.3%; 88.2%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 12 | 14 | 149 | 6.9%; 0%; 8.0%; 85.1%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | Argon gas | 480 | 12 | 2 | 49 | 4 | 3.6%; 0%; 89.1%; 7.3%; 0% |
|
Yes | |||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
|
4:1 | 480 | 2 | 1 | 4 | 8 | 7.7%; 0%; 30.8%; 61.5%; 0% |
|
Yes | ||||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 3 | 11 | 25 | 7.7%; 0%; 28.2%; 64.1%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 |
|
0.1 |
|
|
4:1 | 480 | 12 | 3 | 1 | 75.0%; 0%; 0%; 25.0%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 720 | 9 | 14 | 98 | 7.4%; 0%; 11.6%; 81.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 3 | 7 | 19 | 10.3%; 0%; 24.1%; 65.5%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 40 | 17 | 78 | 29.6%; 0%; 12.6%; 57.8%; 0% |
|
Yes | ||||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 2 | 12 | 14 | 7.1%; 0%; 42.9%; 50.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.05 | 0.1 |
|
|
4:1 | 480 | 12 | 12 | 8 | 157 | 6.8%; 0%; 4.5%; 88.7%; 0% |
|
Yes |
