Photocatalytic CO2 reduction using a Mn complex as a catalyst/Photocatalytic CO2 reduction: conditions optimization

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Mn(bpy)(CO)3Br	0.05		0.05	BNAH	0.1			DMF	TEOA		4:1								480	0.17	2									4						33.3%; 0%; 0%; 66.7%; 0%			No
Mn(bpy)(CO)3Br	0.05		0.05	BNAH	0.1			DMF	TEOA		4:1								480	2	8						1			67						10.5%; 0%; 1.3%; 88.2%; 0%			Yes
Mn(bpy)(CO)3Br	0.05		0.05	BNAH	0.1			DMF	TEOA		4:1								480	12	12						14			149						6.9%; 0%; 8.0%; 85.1%; 0%			Yes
Mn(bpy)(CO)3Br	0.05		0.05	BNAH	0.1			DMF	TEOA		4:1	Argon gas							480	12	2						49			4						3.6%; 0%; 89.1%; 7.3%; 0%			Yes
			0.05	BNAH	0.1			DMF	TEOA		4:1								480	2	1						4			8						7.7%; 0%; 30.8%; 61.5%; 0%			Yes
			0.05	BNAH	0.1			DMF	TEOA		4:1								480	12	3						11			25						7.7%; 0%; 28.2%; 64.1%; 0%			Yes
Mn(bpy)(CO)3Br	0.05			BNAH	0.1			DMF	TEOA		4:1								480	12	3									1						75.0%; 0%; 0%; 25.0%; 0%			No
Mn(bpy)(CO)3Br	0.05		0.05	BNAH	0.1			DMA	TEOA		4:1								480	720	9						14			98						7.4%; 0%; 11.6%; 81.0%; 0%			Yes
			0.05	BNAH	0.1			DMA	TEOA		4:1								480	12	3						7			19						10.3%; 0%; 24.1%; 65.5%; 0%			Yes
Mn(bpy)(CO)3Br	0.05		0.05	BNAH	0.1			MeCN	TEOA		4:1								480	12	40						17			78						29.6%; 0%; 12.6%; 57.8%; 0%			Yes
			0.05	BNAH	0.1			MeCN	TEOA		4:1								480	12	2						12			14						7.1%; 0%; 42.9%; 50.0%; 0%			Yes
Mn(bpy)(CO)3Br	0.05	Ru(bpy)3	0.05	BNAH	0.1			DMF	TEOA		4:1								480	12	12						8			157						6.8%; 0%; 4.5%; 88.7%; 0%			Yes