Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts/Results for photocatalytic reduction of CO2: Difference between revisions

Revision as of 14:40, 10 March 2023

cat	cat conc [µM]	PS conc [mM]	e-D	e-D conc [M]	solvent A	solvent B	solv A/B/C	λexc [nm]	t [h]	TON CO	Φ CO [%]	TON H2	TON HCOOH	Φ HCOOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	include
Molecule:100688	0.05	0.25	BIH	0.01	MeCN	TEOA	4:1	436	2	50	0.02	4	157	0.3	23.7%; 0%; 1.9%; 74.4%; 0%	0.32	Yes
Molecule:100690	0.05	0.25	BIH	0.01	MeCN	TEOA	4:1	436	2	164	0.33	1	65	0.24	71.3%; 0%; 0.4%; 28.3%; 0%	0.57	Yes
Mn(oMesbpy)(CO)2Br	0.05	0.25	BIH	0.01	MeCN	TEOA	4:1	436	2	208	0.41	0.5	5	0.03	97.4%; 0%; 0.2%; 2.3%; 0%	0.44	Yes

@@ Line 1: / Line 1: @@
 {{Photocatalytic CO2 conversion experiments
 |experiments={{Photocatalytic CO2 conversion
+|catalyst=Molecule:100688
+|cat conc=0.05
+|PS conc=0.25
+|e-D=Molecule:100508
+|e-D conc=0.01
+|solvent A=Molecule:100530
+|solvent B=Molecule:100507
+|solvent-ratio=4:1
+|λexc=436
+|irr time=2
+|TON CO=50
+|Φ CO=0.02
+|TON H2=4
+|TON HCOOH=157
+|Φ HCOOH=0.3
+|include=Yes
+}}{{Photocatalytic CO2 conversion
+|catalyst=Molecule:100690
 |cat conc=0.05
 |PS conc=0.25
@@ Line 17: / Line 35: @@
 |include=Yes
 }}{{Photocatalytic CO2 conversion
-|catalyst=Molecule:100688
+|catalyst=Molecule:100705
 |cat conc=0.05
 |PS conc=0.25
@@ Line 27: / Line 45: @@
 |λexc=436
 |irr time=2
-|TON CO=50
+|TON CO=208
-|Φ CO=0.02
+|Φ CO=0.41
-|TON H2=4
+|TON H2=0.5
-|TON HCOOH=157
+|TON HCOOH=5
-|Φ HCOOH=0.3
+|Φ HCOOH=0.03
 |include=Yes
 }}
 }}