Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light/Table 1: Difference between revisions

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< Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light
investigation
Molecular process, Photocatalytic CO2 conversion experiments
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|catalyst=Molecule:100486
|catalyst=Molecule:100486
|cat conc=3
|cat conc=3
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100610
|cat conc=0.025
|PS=Molecule:100487
|PS conc=0.025
|e-D=Molecule:100507
|solvent A=Molecule:100532
|Temperature=25
|λexc=400 - 700
|TON CO=1
|TON H2=2
|TON HCOOH=13
|include=No
|include=No
}}
}}
}}
}}

Revision as of 13:42, 15 December 2022

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Ru(bpy)3Cl2

3







n/a


No

Molecule:100610

0.025

Molecule:100487

0.025

TEOA


NMP



25 400 - 700 1 2 13 6.3%; 0%; 12.5%; 81.3%; 0%


No