Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light - 2026.07.03/inv0

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Fe1	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	987	41.1					187									84.1%; 0%; 15.9%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	1318	54.9					243									84.4%; 0%; 15.6%; 0%; 0%				"not reported" is not a number.
Fe3	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	847	35.3					205									80.5%; 0%; 19.5%; 0%; 0%				"not reported" is not a number.
Fe4	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	1265	52.7					133									90.5%; 0%; 9.5%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	4	311	77.7					51									85.9%; 0%; 14.1%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	48	1578	32.9					296									84.2%; 0%; 15.8%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	96	1593	16.6					300									84.2%; 0%; 15.8%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11			MeCN			100:0			CO2		not reported	not reported	35	462	24	2	not reported					22									8.3%; 0%; 91.7%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		90:10			CO2		not reported	not reported	35	462	24	1352	56.3					285									82.6%; 0%; 17.4%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		70:30			CO2		not reported	not reported	35	462	24	661	27.5					191									77.6%; 0%; 22.4%; 0%; 0%				"not reported" is not a number.
Fe2	50	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		50:50			CO2		not reported	not reported	35	462	24	621	25.8					77									89.0%; 0%; 11.0%; 0%; 0%				"not reported" is not a number.
Fe2	25	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	2086	86.9					123									94.4%; 0%; 5.6%; 0%; 0%				"not reported" is not a number.
Fe2	12.5	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	4259	177.4					276									93.9%; 0%; 6.1%; 0%; 0%				"not reported" is not a number.
Fe2	6.25	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	10168	423.7					862									92.2%; 0%; 7.8%; 0%; 0%				"not reported" is not a number.
Fe2	3.12	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	24	23138	964.1					2177									91.4%; 0%; 8.6%; 0%; 0%				"not reported" is not a number.
Fe2	3.12	TEA	0.3	BIH	0.11	H2O	not reported	MeCN	H2O		92.5:7.5			CO2		not reported	not reported	35	462	4	9754	2438	8.24				3310									74.7%; 0%; 25.3%; 0%; 0%	8.24			"not reported" is not a number.