Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

Revision as of 17:56, 19 June 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	solvent A	solvent B	solv A/B/C	feedstock gas	intensity [kW/m²]	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON H2	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]
[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	987	41.1 h−1		187	84.1%; 0%; 15.9%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	1318	54.9 h−1		243	84.4%; 0%; 15.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	847	35.3 h−1		205	80.5%; 0%; 19.5%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	1265	52.7 h−1		133	90.5%; 0%; 9.5%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	4 h	311	77.7 h−1		51	85.9%; 0%; 14.1%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	48 h	1578	32.9 h−1		296	84.2%; 0%; 15.8%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	96 h	1593	16.6 h−1		300	84.2%; 0%; 15.8%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN			CO2		308 K	462 nm (blue LED strip)	24 h	2	< 0.1 h−1		22	8.3%; 0%; 91.7%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	90:10	CO2		308 K	462 nm (blue LED strip)	24 h	1352	56.3 h−1		285	82.6%; 0%; 17.4%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	70:30	CO2		308 K	462 nm (blue LED strip)	24 h	661	27.5 h−1		191	77.6%; 0%; 22.4%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	50:50	CO2		308 K	462 nm (blue LED strip)	24 h	621	25.8 h−1		77	89.0%; 0%; 11.0%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	25.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	2086	86.9 h−1		123	94.4%; 0%; 5.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	12.5 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	4259	177.4 h−1		276	93.9%; 0%; 6.1%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	6.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	10168	423.7 h−1		862	92.2%; 0%; 7.8%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.12 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	24 h	23138	964.1 h−1		2177	91.4%; 0%; 8.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2	absorbed photon flux 2.16 × 10−8 einstein s−1	308 K	462 nm	4 h			4.8%		n/a	4.8	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2	absorbed photon flux 2.16 × 10−8 einstein s−1	308 K	462 nm	4 h	9754	2438 h−1	7.6%		n/a	7.6	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2	absorbed photon flux 2.16 × 10−8 einstein s−1	308 K	462 nm	4 h			3.8%		n/a	3.8	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2	absorbed photon flux 2.16 × 10−8 einstein s−1	308 K	462 nm	4 h			7.2%		n/a	7.2	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.12 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	8.24%	MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	4 h	9754	2438 h−1			n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li> <!--br--><li>"h−1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.12 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	2 h	3562			1039	77.4%; 0%; 22.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.12 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		MeCN	H2O	92.5:7.5	CO2		308 K	462 nm (blue LED strip)	72 h	25872			3899	86.9%; 0%; 13.1%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	27.5 mM									24 h	221				n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li></ul>

@@ Line 8: / Line 8: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 39: / Line 39: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 70: / Line 70: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 101: / Line 101: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 132: / Line 132: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=4 h
@@ Line 163: / Line 163: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=48 h
@@ Line 194: / Line 194: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=96 h
@@ Line 226: / Line 226: @@
 |solvent B=
 |solvent-ratio=
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 256: / Line 256: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=10% H2O (v/v)
+|solvent-ratio=90:10
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 287: / Line 287: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=30% H2O (v/v)
+|solvent-ratio=70:30
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 318: / Line 318: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=50% H2O (v/v)
+|solvent-ratio=50:50
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 349: / Line 349: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 380: / Line 380: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
@@ Line 411: / Line 411: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
-|Turnover_number__CO=10
+|Turnover_number__CO=10168
-|Turnover_frequency__CO=168
+|Turnover_frequency__CO=423.7 h−1
-|Turnover_number__H2=423.7 h−1
+|Turnover_number__H2=862
-|Turnover_frequency__H2=862
+|Turnover_frequency__H2=
 |additives=
 |Turnover_number__HCOOH=
@@ Line 442: / Line 442: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
-|Turnover_number__CO=23
+|Turnover_number__CO=23138
-|Turnover_frequency__CO=138
+|Turnover_frequency__CO=964.1 h−1
-|Turnover_number__H2=964.1 h−1
+|Turnover_number__H2=2177
-|Turnover_frequency__H2=2177
+|Turnover_frequency__H2=
 |additives=
 |Turnover_number__HCOOH=
@@ Line 473: / Line 473: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm
 |irr time=4 h
@@ Line 504: / Line 504: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm
 |irr time=4 h
@@ Line 535: / Line 535: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm
 |irr time=4 h
@@ Line 566: / Line 566: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm
 |irr time=4 h
@@ Line 590: / Line 590: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50 μM
+|cat conc=3.12 μM
+|PS=[Ru(bpy)3]2+
+|PS conc=0.3 mM
+|e-D=Molecule:100508
+|e-D conc=0.11 M
+|solvent A=Molecule:100530
+|solvent B=Molecule:100616
+|solvent-ratio=92.5:7.5
+|feedstock gas=CO2
+|Temperature=308 K
+|λexc=462 nm (blue LED strip)
+|irr time=4 h
+|Turnover_number__CO=9754
+|Turnover_frequency__CO=2438 h−1
+|Turnover_number__H2=
+|Turnover_frequency__H2=
+|additives=
+|Turnover_number__HCOOH=
+|intensity=
+|Turnover_number__CH4=
+|additives conc=
+|Quantum_yield__CO=
+|H-D=8.24%
+|H-D conc=
+|solvent C=
+|Quantum_yield__HCOOH=
+|pH=
+|Turnover_frequency__HCOOH=
+}}
+{{Photocatalytic_CO2_conversion
+|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|cat conc=3.12 μM
+|PS=[Ru(bpy)3]2+
+|PS conc=0.3 mM
+|e-D=Molecule:100508
+|e-D conc=0.11 M
+|solvent A=Molecule:100530
+|solvent B=Molecule:100616
+|solvent-ratio=92.5:7.5
+|feedstock gas=CO2
+|Temperature=308 K
+|λexc=462 nm (blue LED strip)
+|irr time=2 h
+|Turnover_number__CO=3562
+|Turnover_frequency__CO=
+|Turnover_number__H2=1039
+|Turnover_frequency__H2=
+|additives=
+|Turnover_number__HCOOH=
+|intensity=
+|Turnover_number__CH4=
+|additives conc=
+|Quantum_yield__CO=
+|H-D=
+|H-D conc=
+|solvent C=
+|Quantum_yield__HCOOH=
+|pH=
+|Turnover_frequency__HCOOH=
+}}
+{{Photocatalytic_CO2_conversion
+|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|cat conc=3.12 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
 |e-D=Molecule:100508
-|e-D conc=27.5 mM
+|e-D conc=0.11 M
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2
-|Temperature=35 °C
+|Temperature=308 K
 |λexc=462 nm (blue LED strip)
+|irr time=72 h
+|Turnover_number__CO=25872
+|Turnover_frequency__CO=
+|Turnover_number__H2=3899
+|Turnover_frequency__H2=
+|additives=
+|Turnover_number__HCOOH=
+|intensity=
+|Turnover_number__CH4=
+|additives conc=
+|Quantum_yield__CO=
+|H-D=
+|H-D conc=
+|solvent C=
+|Quantum_yield__HCOOH=
+|pH=
+|Turnover_frequency__HCOOH=
+}}
+{{Photocatalytic_CO2_conversion
+|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|cat conc=50 μM
+|PS=[Ru(bpy)3]2+
+|PS conc=0.3 mM
+|e-D=Molecule:100508
+|e-D conc=27.5 mM
+|solvent A=
+|solvent B=
+|solvent-ratio=
+|feedstock gas=
+|Temperature=
+|λexc=
 |irr time=24 h
 |Turnover_number__CO=221

Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

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