Pyranopterin Related Dithiolene Molybdenum Complexes as Homogeneous Catalysts for CO2 Photoreduction/Table 1: Difference between revisions

Latest revision as of 14:33, 29 January 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	solvent B	solv A/B/C	T [°C]	λexc [nm]	t [h]	TON CO	TON H2	TON HCOOH	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	include
[MoO(qpdt)2][NBu4]2	50	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	TEOA	5:1	20	400	15	73	670	80	8.9%; 0%; 81.4%; 9.7%; 0%	Yes
[K]2[MoO(Hqpdt)2]	50	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	TEOA	5:1	20	400	15	13	51	31	13.7%; 0%; 53.7%; 32.6%; 0%	Yes
[MoO(2Hqpdt)2][NBu4]	50	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	TEOA	5:1	20	400	15	40	89	83	18.9%; 0%; 42.0%; 39.2%; 0%	Yes

@@ Line 13: / Line 13: @@
 |λexc=400
 |irr time=15
-|TON CO=73
+|Turnover_number__CO=73
-|TON H2=670
+|Turnover_number__H2=670
-|TON HCOOH=80
+|Turnover_number__HCOOH=80
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 30: / Line 30: @@
 |λexc=400
 |irr time=15
-|TON CO=13
+|Turnover_number__CO=13
-|TON H2=51
+|Turnover_number__H2=51
-|TON HCOOH=31
+|Turnover_number__HCOOH=31
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 47: / Line 47: @@
 |λexc=400
 |irr time=15
-|TON CO=40
+|Turnover_number__CO=40
-|TON H2=89
+|Turnover_number__H2=89
-|TON HCOOH=83
+|Turnover_number__HCOOH=83
 |include=Yes
 }}
 }}