Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production/Table 1: Difference between revisions

Latest revision as of 13:33, 29 January 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	solvent B	solv A/B/C	T [°C]	λexc [nm]	t [h]	TON CO	Φ CO [%]	TON H2	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	include
[Ni(bpet)(MeCN)2][ClO4]2	30	Ru(bpy)3Cl2	0.5	BIH	0.1	DMA	H2O	9:1	25	450	55	713	1.42	6.9	99.0%; 0%; 1.0%; 0%; 0%	1.42	Yes
[Ni(bpet)(MeCN)2][ClO4]2	30	Ru(bpy)3Cl2	0.5	BIH	0.1	DMF	H2O	9:1	25	450		159		11	93.5%; 0%; 6.5%; 0%; 0%		Yes
[Ni(bpet)(MeCN)2][ClO4]2	30	Ru(bpy)3Cl2	0.5	BIH	0.1	DMA	H2O	9:1	25	450		67		3.4	95.2%; 0%; 4.8%; 0%; 0%		Yes
[Ni(bpet)(MeCN)2][ClO4]2	30	Ru(bpy)3Cl2	0.5	BIH	0.1	MeCN	H2O	9:1	25	450					n/a		No
[Ni(bpet)(MeCN)2][ClO4]2	30	Ru(bpy)3Cl2	0.5	TEA	0.1	DMA	H2O	9:1	25	450					n/a		No
[Ni(bpet)(MeCN)2][ClO4]2	30	Ru(bpy)3Cl2	0.5	TEOA	0.1	DMA	H2O	9:1	25	450		2.6		25.5	9.3%; 0%; 90.7%; 0%; 0%		Yes

@@ Line 13: / Line 13: @@
 |λexc=450
 |irr time=55
-|TON CO=713
+|Turnover_number__CO=713
-|Φ CO=1.42
+|Quantum_yield__CO=1.42
-|TON H2=6.9
+|Turnover_number__H2=6.9
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 29: / Line 29: @@
 |Temperature=25
 |λexc=450
-|TON CO=159
+|Turnover_number__CO=159
-|TON H2=11
+|Turnover_number__H2=11
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 44: / Line 44: @@
 |Temperature=25
 |λexc=450
-|TON CO=67
+|Turnover_number__CO=67
-|TON H2=3.4
+|Turnover_number__H2=3.4
 |include=Yes
 }}{{Photocatalytic CO2 conversion
@@ Line 85: / Line 85: @@
 |Temperature=25
 |λexc=450
-|TON CO=2.6
+|Turnover_number__CO=2.6
-|TON H2=25.5
+|Turnover_number__H2=25.5
 |include=Yes
 }}
 }}