A Water Soluble Cobalt(II) Complex with 1,10‑Phenanthroline, a Catalyst for Visible‑Light‑Driven Reduction of CO2 to CO with High Selectivity/Table 1

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume [mL]	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TOF CH4 [TOF/min]	Φ CH4 [%]	TON H2	TOF H2 [TOF/min]	Φ H2 [%]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	TON MeOH	TOF MeOH [TOF/min]	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Co(phen)2(CN)2	0	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN	H2O		9:1			CO2					469	10	0															n/a			No
Co(phen)2(CN)2	2.5	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN	H2O		9:1			CO2					469	10	1130															n/a			No
Co(phen)2(CN)2	5	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN	H2O		9:1			CO2					469	10	730															n/a			No
Co(phen)2(CN)2	25	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN	H2O		9:1			CO2					469	10	154															n/a			No
Co(phen)2(CN)2	2.5	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN	H2O		9:1			CO2							0															n/a			No
Co(phen)2(CN)2	0	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN	H2O		9:1			CO2					469	10	0															n/a			No
Co(phen)2(CN)2	2.5	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN	H2O		9:1			nitrogen					469	10	0															n/a			No
Co(phen)2(CN)2	2.5	[Ru(phen)3](PF6)2	0.40					MeCN	H2O		9:1			CO2					469	10	0															n/a			No
Co(phen)2(CN)2	2.5	[Ru(phen)3](PF6)2	0.40	TEOA	0.4			MeCN						CO2					469	10	720															n/a			No
Co(phen)2(CN)2	2.5			TEOA	0.4			MeCN	H2O		9:1			CO2					469	10	0															n/a			No