Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction/Results obtained with Co2+ catalyst: Difference between revisions

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< Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction
investigation
Molecular process, Photocatalytic CO2 conversion experiments
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Line 13: Line 13:
|TOF CO=2.8333333333333
|TOF CO=2.8333333333333
|TOF HCOOH=7.7333333333333
|TOF HCOOH=7.7333333333333
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 28: Line 28:
|TOF CO=2.0333333333333
|TOF CO=2.0333333333333
|TOF HCOOH=8.5333333333333
|TOF HCOOH=8.5333333333333
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 43: Line 43:
|TOF CO=4.2666666666667
|TOF CO=4.2666666666667
|TOF HCOOH=10.916666666667
|TOF HCOOH=10.916666666667
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 58: Line 58:
|TOF CO=10.783333333333
|TOF CO=10.783333333333
|TOF HCOOH=2.2
|TOF HCOOH=2.2
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 73: Line 73:
|TOF CO=6.2666666666667
|TOF CO=6.2666666666667
|TOF HCOOH=3.15
|TOF HCOOH=3.15
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 88: Line 88:
|TOF CO=2
|TOF CO=2
|TOF HCOOH=0.13333333333333
|TOF HCOOH=0.13333333333333
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 103: Line 103:
|TOF CO=0.21666666666667
|TOF CO=0.21666666666667
|TOF HCOOH=0.96666666666667
|TOF HCOOH=0.96666666666667
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 118: Line 118:
|TOF CO=0.23333333333333
|TOF CO=0.23333333333333
|TOF HCOOH=1.2
|TOF HCOOH=1.2
|include=in 5 mL solvent
|details=in 5 mL solvent
}}{{Photocatalytic_CO2_conversion
}}{{Photocatalytic_CO2_conversion
|catalyst=Molecule:100969
|catalyst=Molecule:100969
Line 133: Line 133:
|TOF CO=0.3
|TOF CO=0.3
|TOF HCOOH=0.48333333333333
|TOF HCOOH=0.48333333333333
|include=in 5 mL solvent
|details=in 5 mL solvent
}}
}}
}}
}}

Latest revision as of 22:51, 22 November 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100969

2

Ru(bpy)3

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90 2.8333333333333 7.7333333333333 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90 2.0333333333333 8.5333333333333 n/a


in 5 mL solvent

Molecule:100969

2

Ir(ppy)3

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 4.2666666666667 10.916666666667 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 10.783333333333 2.2 n/a


in 5 mL solvent

Molecule:100969

2

Ru(bpy)3

0.2

BIH

0.05

PhOH

1

MeCN



CO2 90 6.2666666666667 3.15 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

PhOH

1

MeCN



CO2 90 2 0.13333333333333 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

PhOH

0.5

MeCN



CO2 90 0.21666666666667 0.96666666666667 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

Molecule:100972

0.1

MeCN



CO2 90 0.23333333333333 1.2 n/a


in 5 mL solvent

Molecule:100969

2

Molecule:100971

0.2

TEA

0.05

TFE

0.1

MeCN



CO2 90 0.3 0.48333333333333 n/a


in 5 mL solvent