Photocatalytic CO2 reduction with aminoanthraquinone organic dyes/Photocatalytic CO2 reduction with varying concentrations of cat and PS: Difference between revisions

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< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
investigation
Molecular process, Photocatalytic CO2 conversion experiments
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|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.0005
|cat conc=0.5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.0005
|PS conc=0.0005
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.001
|cat conc=1
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.001
|PS conc=0.001
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.002
|PS conc=0.002
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.005
|cat conc=5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.0005
|cat conc=0.5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.0006
|cat conc=0.6
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.001
|cat conc=1
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.02
|cat conc=20
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.05
|cat conc=50
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.015
|PS conc=0.015
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.005
|cat conc=5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.02
|cat conc=20
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.005
|cat conc=5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.02
|cat conc=20
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005

Latest revision as of 17:21, 10 March 2025

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.5

Molecule:100932

0.0005

BIH

0.06


DMF



> 400 3174 n/a


No

Fe(DHPP)Cl

1

Molecule:100932

0.001

BIH

0.06


DMF



> 400 3587 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.002

BIH

0.06


DMF



> 400 3817 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.005

BIH

0.06


DMF



> 400 4978 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

0.5

Molecule:100932

0.02

BIH

0.06


DMF



> 400 19158 n/a


No

Fe(DHPP)Cl

0.6

Molecule:100932

0.02

BIH

0.06


DMF



> 400 21616 n/a


No

Fe(DHPP)Cl

1

Molecule:100932

0.02

BIH

0.06


DMF



> 400 17020 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.02

BIH

0.06


DMF



> 400 11250 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.02

BIH

0.06


DMF



> 400 3942 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.02

BIH

0.06


DMF



> 400 2134 n/a


No

Fe(DHPP)Cl

50

Molecule:100932

0.02

BIH

0.06


DMF



> 400 891 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.015

BIH

0.06


DMF



> 400 8772 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.01

BIH

0.06


DMF



> 400 5593 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4128 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.01

BIH

0.06


DMF



> 400 2325 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.005

BIH

0.06


DMF



> 400 8780 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.005

BIH

0.06


DMF



> 400 5258 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.005

BIH

0.06


DMF



> 400 2576 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.005

BIH

0.06


DMF



> 400 1539 n/a


No