Photocatalytic CO2 reduction with aminoanthraquinone organic dyes/Photocatalytic CO2 reduction with varying concentrations of cat and PS: Difference between revisions

From ChemWiki
< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
investigation
Molecular process, Photocatalytic CO2 conversion experiments
← Older edit
VisualWikitext
Laura (talk | contribs)
270 edits
No edit summary
cleanup template params
 
(2 intermediate revisions by one other user not shown)
Line 2: Line 2:
|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.0005
|cat conc=0.5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.0005
|PS conc=0.0005
Line 9: Line 9:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=3174
|Turnover_number__CO=3174
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.001
|cat conc=1
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.001
|PS conc=0.001
Line 20: Line 20:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=3587
|Turnover_number__CO=3587
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.002
|PS conc=0.002
Line 31: Line 31:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=3817
|Turnover_number__CO=3817
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.005
|cat conc=5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
Line 42: Line 42:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=4978
|Turnover_number__CO=4978
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
Line 53: Line 53:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=4028
|Turnover_number__CO=4028
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.0005
|cat conc=0.5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
Line 64: Line 64:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=19158
|Turnover_number__CO=19158
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.0006
|cat conc=0.6
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
Line 75: Line 75:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=21616
|Turnover_number__CO=21616
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.001
|cat conc=1
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
Line 86: Line 86:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=17020
|Turnover_number__CO=17020
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
Line 97: Line 97:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=11250
|Turnover_number__CO=11250
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
Line 108: Line 108:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=3942
|Turnover_number__CO=3942
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.02
|cat conc=20
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
Line 119: Line 119:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=2134
|Turnover_number__CO=2134
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.05
|cat conc=50
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.02
|PS conc=0.02
Line 130: Line 130:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=891
|Turnover_number__CO=891
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.015
|PS conc=0.015
Line 141: Line 141:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=8772
|Turnover_number__CO=8772
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
Line 152: Line 152:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=5593
|Turnover_number__CO=5593
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.005
|cat conc=5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
Line 163: Line 163:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=4128
|Turnover_number__CO=4128
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
Line 174: Line 174:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=4028
|Turnover_number__CO=4028
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.02
|cat conc=20
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
Line 185: Line 185:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=2325
|Turnover_number__CO=2325
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
Line 196: Line 196:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=8780
|Turnover_number__CO=8780
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.005
|cat conc=5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
Line 207: Line 207:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=5258
|Turnover_number__CO=5258
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
Line 218: Line 218:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=2576
|Turnover_number__CO=2576
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.02
|cat conc=20
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
Line 229: Line 229:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=1539
|Turnover_number__CO=1539
|include=No
|include=No
}}
}}
}}
}}

Latest revision as of 13:33, 29 January 2026

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.5

Molecule:100932

0.0005

BIH

0.06


DMF



> 400 3174 n/a


No

Fe(DHPP)Cl

1

Molecule:100932

0.001

BIH

0.06


DMF



> 400 3587 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.002

BIH

0.06


DMF



> 400 3817 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.005

BIH

0.06


DMF



> 400 4978 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

0.5

Molecule:100932

0.02

BIH

0.06


DMF



> 400 19158 n/a


No

Fe(DHPP)Cl

0.6

Molecule:100932

0.02

BIH

0.06


DMF



> 400 21616 n/a


No

Fe(DHPP)Cl

1

Molecule:100932

0.02

BIH

0.06


DMF



> 400 17020 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.02

BIH

0.06


DMF



> 400 11250 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.02

BIH

0.06


DMF



> 400 3942 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.02

BIH

0.06


DMF



> 400 2134 n/a


No

Fe(DHPP)Cl

50

Molecule:100932

0.02

BIH

0.06


DMF



> 400 891 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.015

BIH

0.06


DMF



> 400 8772 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.01

BIH

0.06


DMF



> 400 5593 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4128 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.01

BIH

0.06


DMF



> 400 2325 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.005

BIH

0.06


DMF



> 400 8780 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.005

BIH

0.06


DMF



> 400 5258 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.005

BIH

0.06


DMF



> 400 2576 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.005

BIH

0.06


DMF



> 400 1539 n/a


No
Retrieved from "https://chemwiki.scc.kit.edu/main/mediawiki/index.php?title=Photocatalytic_CO2_reduction_with_aminoanthraquinone_organic_dyes/Photocatalytic_CO2_reduction_with_varying_concentrations_of_cat_and_PS&oldid=10310"
Powered by MediaWiki
Powered by Semantic MediaWiki