Photocatalytic CO2 reduction with aminoanthraquinone organic dyes/Photocatalytic CO2 reduction with varying concentrations of cat and PS: Difference between revisions

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< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
investigation
Molecular process, Photocatalytic CO2 conversion experiments
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Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100671 |cat conc=0.0005 |PS=Molecule:100932 |PS conc=0.0005 |e-D=Molecule:100508 |e-D conc=0.06 |solvent A=Molecule:100529 |λexc=> 400 |TON CO=3174 |include=No }}{{Photocatalytic CO2 conversion |catalyst=Molecule:100671 |cat conc=0.001 |PS=Molecule:100932 |PS conc=0.001 |e-D=Molecule:100508 |e-D conc=0.06 |solvent A=Molecule:100529 |λexc=> 400 |TON CO=3587 |inclu..."
 
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|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.0005
|cat conc=0.5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.0005
|PS conc=0.0005
Line 9: Line 9:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=3174
|Turnover_number__CO=3174
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.001
|cat conc=1
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.001
|PS conc=0.001
Line 20: Line 20:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=3587
|Turnover_number__CO=3587
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.002
|cat conc=2
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.002
|PS conc=0.002
Line 31: Line 31:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=3817
|Turnover_number__CO=3817
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.005
|cat conc=5
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.005
|PS conc=0.005
Line 42: Line 42:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=4978
|Turnover_number__CO=4978
|include=No
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|catalyst=Molecule:100671
|cat conc=0.01
|cat conc=10
|PS=Molecule:100932
|PS=Molecule:100932
|PS conc=0.01
|PS conc=0.01
Line 53: Line 53:
|solvent A=Molecule:100529
|solvent A=Molecule:100529
|λexc=> 400
|λexc=> 400
|TON CO=4028
|Turnover_number__CO=4028
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=0.5
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=19158
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=0.6
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=21616
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=1
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=17020
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=2
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=11250
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=10
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=3942
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=20
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=2134
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=50
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=891
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=2
|PS=Molecule:100932
|PS conc=0.015
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=8772
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=2
|PS=Molecule:100932
|PS conc=0.01
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=5593
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=5
|PS=Molecule:100932
|PS conc=0.01
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=4128
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=10
|PS=Molecule:100932
|PS conc=0.01
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=4028
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=20
|PS=Molecule:100932
|PS conc=0.01
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=2325
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=2
|PS=Molecule:100932
|PS conc=0.005
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=8780
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=5
|PS=Molecule:100932
|PS conc=0.005
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=5258
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=10
|PS=Molecule:100932
|PS conc=0.005
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=2576
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=20
|PS=Molecule:100932
|PS conc=0.005
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=> 400
|Turnover_number__CO=1539
|include=No
|include=No
}}
}}
}}
}}

Latest revision as of 13:33, 29 January 2026

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.5

Molecule:100932

0.0005

BIH

0.06


DMF



> 400 3174 n/a


No

Fe(DHPP)Cl

1

Molecule:100932

0.001

BIH

0.06


DMF



> 400 3587 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.002

BIH

0.06


DMF



> 400 3817 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.005

BIH

0.06


DMF



> 400 4978 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

0.5

Molecule:100932

0.02

BIH

0.06


DMF



> 400 19158 n/a


No

Fe(DHPP)Cl

0.6

Molecule:100932

0.02

BIH

0.06


DMF



> 400 21616 n/a


No

Fe(DHPP)Cl

1

Molecule:100932

0.02

BIH

0.06


DMF



> 400 17020 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.02

BIH

0.06


DMF



> 400 11250 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.02

BIH

0.06


DMF



> 400 3942 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.02

BIH

0.06


DMF



> 400 2134 n/a


No

Fe(DHPP)Cl

50

Molecule:100932

0.02

BIH

0.06


DMF



> 400 891 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.015

BIH

0.06


DMF



> 400 8772 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.01

BIH

0.06


DMF



> 400 5593 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4128 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.01

BIH

0.06


DMF



> 400 4028 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.01

BIH

0.06


DMF



> 400 2325 n/a


No

Fe(DHPP)Cl

2

Molecule:100932

0.005

BIH

0.06


DMF



> 400 8780 n/a


No

Fe(DHPP)Cl

5

Molecule:100932

0.005

BIH

0.06


DMF



> 400 5258 n/a


No

Fe(DHPP)Cl

10

Molecule:100932

0.005

BIH

0.06


DMF



> 400 2576 n/a


No

Fe(DHPP)Cl

20

Molecule:100932

0.005

BIH

0.06


DMF



> 400 1539 n/a


No
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