Photocatalytic CO2 reduction with aminoanthraquinone organic dyes/Photocatalytic reduction of CO2 with different photosensitizers: Difference between revisions
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|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.6 | ||
|PS=Molecule:100930 | |PS=Molecule:100930 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 10: | Line 10: | ||
|λexc=>400 | |λexc=>400 | ||
|irr time=48 | |irr time=48 | ||
| | |Turnover_number__CO=2395 | ||
| | |Turnover_frequency__CO=1510 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.6 | ||
|PS=Molecule:100958 | |PS=Molecule:100958 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 23: | Line 23: | ||
|λexc=>400 | |λexc=>400 | ||
|irr time=48 | |irr time=48 | ||
| | |Turnover_number__CO=2738 | ||
| | |Turnover_frequency__CO=69 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.6 | ||
|PS=Molecule:100959 | |PS=Molecule:100959 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 36: | Line 36: | ||
|λexc=>400 | |λexc=>400 | ||
|irr time=48 | |irr time=48 | ||
| | |Turnover_number__CO=3551 | ||
| | |Turnover_frequency__CO=593 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.6 | ||
|PS=Molecule:100931 | |PS=Molecule:100931 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 49: | Line 49: | ||
|λexc=>400 | |λexc=>400 | ||
|irr time=48 | |irr time=48 | ||
| | |Turnover_number__CO=8360 | ||
| | |Turnover_frequency__CO=1614 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.6 | ||
|PS=Molecule:100932 | |PS=Molecule:100932 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 62: | Line 62: | ||
|λexc=>400 | |λexc=>400 | ||
|irr time=48 | |irr time=48 | ||
| | |Turnover_number__CO=21616 | ||
| | |Turnover_frequency__CO=4028 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.6 | ||
|PS=Molecule:100933 | |PS=Molecule:100933 | ||
|PS conc=0.02 | |PS conc=0.02 | ||
| Line 75: | Line 75: | ||
|λexc=>400 | |λexc=>400 | ||
|irr time=48 | |irr time=48 | ||
| | |Turnover_number__CO=907 | ||
| | |Turnover_frequency__CO=93 | ||
|include=No | |include=No | ||
}} | }} | ||
}} | }} | ||
Latest revision as of 13:33, 29 January 2026
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.6 | 0.02 | 0.06 |
|
|
|
>400 | 48 | 2395 | 1510 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.6 | 0.02 | 0.06 |
|
|
|
>400 | 48 | 2738 | 69 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.6 | 0.02 | 0.06 |
|
|
|
>400 | 48 | 3551 | 593 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.6 | 0.02 | 0.06 |
|
|
|
>400 | 48 | 8360 | 1614 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.6 | 0.02 | 0.06 |
|
|
|
>400 | 48 | 21616 | 4028 | n/a |
|
Yes | ||||||||||||||||||||||||||||
| 0.6 | 0.02 | 0.06 |
|
|
|
>400 | 48 | 907 | 93 | n/a |
|
No |
