Photocatalytic CO2 reduction with aminoanthraquinone organic dyes/Photocatalytic reduction of CO2 with different photosensitizers: Difference between revisions

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< Photocatalytic CO2 reduction with aminoanthraquinone organic dyes
investigation
Molecular process, Photocatalytic CO2 conversion experiments
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|TON CO=2738
|TON CO=2738
|TOF CO=69
|TOF CO=69
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=0.0006
|PS=Molecule:100959
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=>400
|irr time=48
|TON CO=3551
|TOF CO=593
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=0.0006
|PS=Molecule:100931
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=>400
|irr time=48
|TON CO=8360
|TOF CO=1614
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=0.0006
|PS=Molecule:100932
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=>400
|irr time=48
|TON CO=21616
|TOF CO=4028
|include=Yes
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100671
|cat conc=0.0006
|PS=Molecule:100933
|PS conc=0.02
|e-D=Molecule:100508
|e-D conc=0.06
|solvent A=Molecule:100529
|λexc=>400
|irr time=48
|TON CO=907
|TOF CO=93
|include=No
|include=No
}}
}}
}}
}}

Latest revision as of 09:48, 17 May 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Fe(DHPP)Cl

0.0006

Molecule:100930

0.02

BIH

0.06


DMF



>400 48 2395 1510 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100958

0.02

BIH

0.06


DMF



>400 48 2738 69 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100959

0.02

BIH

0.06


DMF



>400 48 3551 593 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100931

0.02

BIH

0.06


DMF



>400 48 8360 1614 n/a


No

Fe(DHPP)Cl

0.0006

Molecule:100932

0.02

BIH

0.06


DMF



>400 48 21616 4028 n/a


Yes

Fe(DHPP)Cl

0.0006

Molecule:100933

0.02

BIH

0.06


DMF



>400 48 907 93 n/a


No