Highly efficient and selective visible-light driven CO2-to-CO conversion by a Co-based cryptate in H2O-CH3CN solution/photocatalytic CO2 conversion under different conditions

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100956	0.000025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25	450	10	33792	0.94														n/a			No
Molecule:100957	0.000025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25	450	10	18656	0.52														n/a			No
		[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25	450	10	0															n/a			No
Molecule:100957	0.000025			TEOA	0.3			MeCN	H2O		4:1			CO2				25	450	10	0															n/a			No
Molecule:100957	0.000025	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25		10	0															n/a			No
Molecule:100957	0.000025	[Ru(phen)3][PF6]2	0.4					MeCN	H2O		4:1			CO2				25	450	10	0															n/a			No
Molecule:100957	0.0005	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25	450	10	600	0.017														n/a			No
Molecule:100957	0.001	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25	450	10	1582	0.04														n/a			No
Molecule:100957	0.0000125	[Ru(phen)3][PF6]2	0.4	TEOA	0.3			MeCN	H2O		4:1			CO2				25	450	10	51392	1.43														n/a			Yes