Photocatalytic Reduction of CO2 by Highly Efficient Homogeneous FeII Catalyst based on 2,6-Bis(1’,2’,3’-triazolyl-methyl)pyridine. Comparison with Analogues./Optimization of CO2 reduction conditions: Difference between revisions

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|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.03
|cat conc=33
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=0.33
|PS conc=0.33
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.03
|cat conc=33
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.01
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
|e-D=Molecule:100508
|e-D=Molecule:100508
|e-D conc=0.1
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent B=Molecule:100507
Line 119: Line 119:
|TON CO=7.4
|TON CO=7.4
|TON H2=6.4
|TON H2=6.4
|include=Yes
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
Line 153: Line 153:
|TON CO=80
|TON CO=80
|TON H2=34
|TON H2=34
|include=Yes
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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|TON CO=0
|TON CO=0
|TON H2=1
|TON H2=1
|include=Yes
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|e-D=Molecule:100508
|e-D=Molecule:100508
|e-D conc=0.02
|e-D conc=0.02
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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|TON CO=0
|TON CO=0
|TON H2=0
|TON H2=0
|include=Yes
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
Line 251: Line 251:
|TON CO=93
|TON CO=93
|TON H2=50
|TON H2=50
|include=Yes
|include=No
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|catalyst=Molecule:100941
|cat conc=0.1
|cat conc=10
|PS=Molecule:100940
|PS=Molecule:100940
|PS conc=1.0
|PS conc=1.0
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|TON CO=450
|TON CO=450
|TON H2=348
|TON H2=348
|include=Yes
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|cat conc=10
|PS=Molecule:100940
|PS conc=1.0
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=5:1
|feedstock gas=CO2
|Temperature=22
|λexc=420
|irr time=4
|TON CO=6.8
|TON CH4=0
|TON H2=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|cat conc=10
|PS=Molecule:100940
|PS conc=1.0
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|feedstock gas=CO2
|Temperature=22
|λexc=420
|irr time=4
|TON CO=44
|TON CH4=1.16
|TON H2=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|cat conc=10
|PS=Molecule:100940
|PS conc=1.0
|solvent A=Molecule:100530
|feedstock gas=CO2
|Temperature=22
|λexc=420
|irr time=4
|TON CO=0
|TON CH4=0
|TON H2=0
|include=No
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100941
|cat conc=10
|PS=Molecule:100940
|PS conc=1.0
|e-D=Molecule:100508
|e-D conc=0.02
|solvent A=Molecule:100530
|solvent B=Molecule:100507
|solvent-ratio=8:1
|feedstock gas=CO2
|Temperature=22
|λexc=420
|irr time=4
|TON CO=0
|TON CH4=0
|TON H2=0
|include=No
}}
}}
}}
}}

Latest revision as of 12:38, 11 March 2025

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume [mL] intensity [kW/m²] pH T [°C] λexc [nm] t [h] TON CO TOF CO [TOF/min] Φ CO [%] TON CH4 TOF CH4 [TOF/min] Φ CH4 [%] TON H2 TOF H2 [TOF/min] Φ H2 [%] TON HCOOH TOF HCOOH [TOF/min] Φ HCOOH [%] TON MeOH TOF MeOH [TOF/min] Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 4 107 43 71.3%; 0%; 28.7%; 0%; 0%


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 20 109 54 66.9%; 0%; 33.1%; 0%; 0%


No

Molecule:100941

33

Molecule:100940

0.33

BIH

0.00666


MeCN

TEOA


5:1 CO2 22 420 4 238 137 63.5%; 0%; 36.5%; 0%; 0%


No

Molecule:100941

33

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 4 314 151 67.5%; 0%; 32.5%; 0%; 0%


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 4 576 287 66.7%; 0%; 33.3%; 0%; 0%


Yes

Molecule:100941

10

Molecule:100940

1.0

BIH

0.1


MeCN

TEOA


5:1 CO2 22 420 4 80 33 70.8%; 0%; 29.2%; 0%; 0%


Yes

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 water CO2 22 420 4 7.4 6.4 53.6%; 0%; 46.4%; 0%; 0%


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 1 3.2 1.6 66.7%; 0%; 33.3%; 0%; 0%


Yes

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 2 80 34 70.2%; 0%; 29.8%; 0%; 0%


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 3 100 43 69.9%; 0%; 30.1%; 0%; 0%


Yes


Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 4 0 1 n/a


No

Molecule:100941

10


BIH

0.02


MeCN

TEOA


5:1 CO2 22 420 4 0 0 n/a


Yes

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 4 0 0 n/a


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 none 22 420 4 0 0 n/a


Yes

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 Hg CO2 22 420 4 93 50 65.0%; 0%; 35.0%; 0%; 0%


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


5:1 CO2 22 solar simulator 4 450 348 56.4%; 0%; 43.6%; 0%; 0%


No

Molecule:100941

10

Molecule:100940

1.0



MeCN

TEOA


5:1 CO2 22 420 4 6.8 0 0 n/a


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN



CO2 22 420 4 44 1.16 0 97.4%; 2.6%; 0%; 0%; 0%


No

Molecule:100941

10

Molecule:100940

1.0



MeCN



CO2 22 420 4 0 0 0 n/a


No

Molecule:100941

10

Molecule:100940

1.0

BIH

0.02


MeCN

TEOA


8:1 CO2 22 420 4 0 0 0 n/a


No
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