Photocatalytic CO2 Reduction Mediated by Electron Transfer via the Excited Triplet State of Zn(II) Porphyrin/photocatalytic CO2 conversion

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
(Zn(tBuPP))-(Re(Phen)Br(CO)3)	0.05			BIH	0.05			DMA				phenol	0.1	CO2					420 nm	40	910		8													n/a	8		No
(Zn(tBuPP))-(Re(Phen)Br(CO)3)	0.075			BIH	0.05			DMA				phenol	0.1	CO2					420 nm	60	1340															n/a		Addition of 500 equivalents (0.025 M) of BIH to the first experiment after 48 h.	No
(Zn(tBuPP))-(Re(Phen)Br(CO)3)	0.05			BIH	0.05			DMA						CO2					420 nm	48	520															n/a			No