Photocatalytic CO2 Reduction under Visible-Light Irradiation by Ruthenium CNC Pincer Complexes/Conditions optimizations for photocatalytic reduction of CO2: Difference between revisions
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| Line 13: | Line 13: | ||
|λexc=450 W Hg lamp, K2CrO4 filter | |λexc=450 W Hg lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
| | |Turnover_number__CO=129 | ||
| | |Turnover_number__H2=556 | ||
| | |Turnover_number__HCOOH=3296 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
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|λexc=450 W Hg lamp, K2CrO4 filter | |λexc=450 W Hg lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
| | |Turnover_number__CO=224 | ||
| | |Turnover_number__H2=1438 | ||
| | |Turnover_number__HCOOH=4593 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 47: | Line 47: | ||
|λexc=450 W Hg lamp, K2CrO4 filter | |λexc=450 W Hg lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
| | |Turnover_number__CO=129 | ||
| | |Turnover_number__H2=505 | ||
| | |Turnover_number__HCOOH=3792 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 64: | Line 64: | ||
|λexc=450 W Hg lamp, K2CrO4 filter | |λexc=450 W Hg lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
| | |Turnover_number__CO=300 | ||
| | |Turnover_number__H2=1897 | ||
| | |Turnover_number__HCOOH=5634 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 91: | Line 91: | ||
|λexc=450 W Hg lamp, K2CrO4 filter | |λexc=450 W Hg lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
| | |Turnover_number__CO=8.9 | ||
| | |Turnover_number__H2=87 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 105: | Line 105: | ||
|λexc=450 W Hg lamp, K2CrO4 filter | |λexc=450 W Hg lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
| | |Turnover_number__H2=20 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 120: | Line 120: | ||
|λexc=450 W Hg lamp, K2CrO4 filter | |λexc=450 W Hg lamp, K2CrO4 filter | ||
|irr time=24 | |irr time=24 | ||
| | |Turnover_number__H2=307 | ||
|include=No | |include=No | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
Latest revision as of 13:33, 29 January 2026
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | CO2 | 450 W Hg lamp, K2CrO4 filter | 24 | 129 | 556 | 3296 | 3.2%; 0%; 14.0%; 82.8%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | CO2 | 450 W Hg lamp, K2CrO4 filter | 24 | 224 | 1438 | 4593 | 3.6%; 0%; 23.0%; 73.4%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | CO2 | 450 W Hg lamp, K2CrO4 filter | 24 | 129 | 505 | 3792 | 2.9%; 0%; 11.4%; 85.7%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | CO2 | 450 W Hg lamp, K2CrO4 filter | 24 | 300 | 1897 | 5634 | 3.8%; 0%; 24.2%; 71.9%; 0% |
|
Yes | ||||||||||||||||||||||||||
|
|
0.05 | 0.1 |
|
|
4:1 | CO2 | 450 W Hg lamp, K2CrO4 filter | 24 | n/a |
|
No | |||||||||||||||||||||||||||||
| 0.01 |
|
0.1 |
|
|
4:1 | CO2 | 450 W Hg lamp, K2CrO4 filter | 24 | 8.9 | 87 | 9.3%; 0%; 90.7%; 0%; 0% |
|
No | |||||||||||||||||||||||||||
| 0.01 | 0.05 |
|
|
|
4:1 | CO2 | 450 W Hg lamp, K2CrO4 filter | 24 | 20 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | argon | 450 W Hg lamp, K2CrO4 filter | 24 | 307 | n/a |
|
No | ||||||||||||||||||||||||||||
| 0.01 | 0.05 | 0.1 |
|
|
4:1 | CO2 | dark | n/a |
|
No |
