Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore/Photocatalytic CO2 reduction: best results: Difference between revisions
From ChemWiki
investigation
No edit summary |
Jana.alpin (talk | contribs) No edit summary |
||
| (4 intermediate revisions by one other user not shown) | |||
| Line 2: | Line 2: | ||
|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.2 | ||
|PS=Molecule:100499 | |||
|PS conc=0.1 | |PS conc=0.1 | ||
|e-D=Molecule:100508 | |e-D=Molecule:100508 | ||
| Line 11: | Line 12: | ||
|TON CO=88 | |TON CO=88 | ||
|TOF CO=45 | |TOF CO=45 | ||
|TON H2=0 | |TON H2=0 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.2 | ||
|PS=Molecule:100771 | |PS=Molecule:100771 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
| Line 30: | Line 30: | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100671 | |catalyst=Molecule:100671 | ||
|cat conc=0. | |cat conc=0.2 | ||
|PS=Molecule:100771 | |PS=Molecule:100771 | ||
|PS conc=0.1 | |PS conc=0.1 | ||
| Line 54: | Line 54: | ||
|TON CO=4.4 | |TON CO=4.4 | ||
|TOF CO=4.3 | |TOF CO=4.3 | ||
|TON H2=0 | |||
|include=Yes | |include=Yes | ||
}} | }} | ||
}} | }} | ||
Latest revision as of 16:42, 10 March 2025
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.2 | 0.1 | 0.01 |
|
|
|
>400 | 7 | 88 | 45 | 0 | n/a |
|
Yes | |||||||||||||||||||||||||||
| 0.2 | 0.1 | 0.01 |
|
|
|
>400 | 7 | 4779 | 1356 | 270 | 94.7%; 0%; 5.3%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 0.2 | 0.1 | 0.1 |
|
|
|
>400 | 23 | 16109 | 7650 | 843 | 95.0%; 0%; 5.0%; 0%; 0% |
|
Yes | |||||||||||||||||||||||||||
| 0 | 0.1 | 0.1 |
|
|
|
>400 | 1 | 4.4 | 4.3 | 0 | n/a |
|
Yes |
