Ir(tpy)(bpy)Cl as a Photocatalyst for CO2 Reduction under Visible-Light Irradiation/Photoreduction of CO2

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Ir(bpy)(tpy)Cl][PF6]2	0.1			TEOA				MeCN	TEOA		5:1			CO2					410 - 750 nm	24	2						1			20						8.7%; 0%; 4.3%; 87.0%; 0%			Yes
[Ir(dmbpy)(tpy)Cl][PF6]2	0.1			TEOA				MeCN	TEOA		5:1			CO2					410 - 750 nm	24	5						3			9						29.4%; 0%; 17.6%; 52.9%; 0%			Yes
[Ir(dnbpy)(tpy)Cl][PF6]2	0.1			TEOA				MeCN	TEOA		5:1			CO2					410 - 750 nm	24	3						1			5						33.3%; 0%; 11.1%; 55.6%; 0%			Yes
Molecule:100869	0.1			TEOA				MeCN	TEOA		5:1			CO2					410 - 750 nm	8	0						1			7						0%; 0%; 12.5%; 87.5%; 0%			Yes