Ir(tpy)(bpy)Cl as a Photocatalyst for CO2 Reduction under Visible-Light Irradiation/Photoreduction of CO2: Difference between revisions
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< Ir(tpy)(bpy)Cl as a Photocatalyst for CO2 Reduction under Visible-Light Irradiation
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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| Line 7: | Line 7: | ||
|solvent B=Molecule:100507 | |solvent B=Molecule:100507 | ||
|solvent-ratio=5:1 | |solvent-ratio=5:1 | ||
|feedstock gas= | |feedstock gas=CO2 | ||
|λexc=410 - 750 nm | |λexc=410 - 750 nm | ||
|irr time=24 | |irr time=24 | ||
| Line 15: | Line 15: | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100867 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|e-D=Molecule:100507 | |e-D=Molecule:100507 | ||
| Line 21: | Line 21: | ||
|solvent B=Molecule:100507 | |solvent B=Molecule:100507 | ||
|solvent-ratio=5:1 | |solvent-ratio=5:1 | ||
|feedstock gas= | |feedstock gas=CO2 | ||
|λexc=410 - 750 nm | |λexc=410 - 750 nm | ||
|irr time=24 | |irr time=24 | ||
|TON CO= | |TON CO=5 | ||
|TON H2=3 | |||
|TON HCOOH=9 | |||
|include=Yes | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100868 | |||
|cat conc=0.1 | |||
|e-D=Molecule:100507 | |||
|solvent A=Molecule:100530 | |||
|solvent B=Molecule:100507 | |||
|solvent-ratio=5:1 | |||
|feedstock gas=CO2 | |||
|λexc=410 - 750 nm | |||
|irr time=24 | |||
|TON CO=3 | |||
|TON H2=1 | |||
|TON HCOOH=5 | |||
|include=Yes | |||
}}{{Photocatalytic CO2 conversion | |||
|catalyst=Molecule:100869 | |||
|cat conc=0.1 | |||
|e-D=Molecule:100507 | |||
|solvent A=Molecule:100530 | |||
|solvent B=Molecule:100507 | |||
|solvent-ratio=5:1 | |||
|feedstock gas=CO2 | |||
|λexc=410 - 750 nm | |||
|irr time=8 | |||
|TON CO=0 | |||
|TON H2=1 | |TON H2=1 | ||
|TON HCOOH= | |TON HCOOH=7 | ||
|include=Yes | |include=Yes | ||
}} | }} | ||
}} | }} | ||
Latest revision as of 13:40, 26 February 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.1 |
|
|
|
5:1 | CO2 | 410 - 750 nm | 24 | 2 | 1 | 20 | 8.7%; 0%; 4.3%; 87.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.1 |
|
|
|
5:1 | CO2 | 410 - 750 nm | 24 | 5 | 3 | 9 | 29.4%; 0%; 17.6%; 52.9%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.1 |
|
|
|
5:1 | CO2 | 410 - 750 nm | 24 | 3 | 1 | 5 | 33.3%; 0%; 11.1%; 55.6%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.1 |
|
|
|
5:1 | CO2 | 410 - 750 nm | 8 | 0 | 1 | 7 | 0%; 0%; 12.5%; 87.5%; 0% |
|
Yes |
