An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2/Effect of proton donor

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMF	TEOA		4:1	water							405 nm	24							4.25			25						0%; 0%; 14.5%; 85.5%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMF	TEOA		4:1	water							405 nm	24							5.75			25.75						0%; 0%; 18.3%; 81.7%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMF	TEOA		4:1	phenol							405 nm	24							5.25			27						0%; 0%; 16.3%; 83.7%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMF	TEOA		4:1	phenol							405 nm	24							5.75			19						0%; 0%; 23.2%; 76.8%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEA				DMF	TEA		4:1	water							405 nm	24							2			12.5						0%; 0%; 13.8%; 86.2%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEA				DMF	TEA		4:1	water							405 nm	24							2.75			14.5						0%; 0%; 15.9%; 84.1%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEA				DMF	TEA		4:1	phenol							405 nm	24							1			10.25						0%; 0%; 8.9%; 91.1%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEA				DMF	TEA		4:1	phenol							405 nm	24							16.25			11.25						0%; 0%; 59.1%; 40.9%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMA	TEOA		4:1	water							405 nm	24							3.25			20.5						0%; 0%; 13.7%; 86.3%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMA	TEOA		4:1	water							405 nm	24							3.5			24						0%; 0%; 12.7%; 87.3%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMA	TEOA		4:1	phenol							405 nm	24							7.75			30						0%; 0%; 20.5%; 79.5%; 0%			No
[Re(bpy)2(CO)2][OTf]		[Ru(bpy)3][PF6]		TEOA				DMA	TEOA		4:1	phenol							405 nm	24							9			34.75						0%; 0%; 20.6%; 79.4%; 0%			No