Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst/Photocatalytic reduction of CO2: Difference between revisions
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< Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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m (Victor.larignon moved page Photocatalytic reduction of CO2 to Photocatalytic reduction of CO2) |
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|e-D conc=0.1 | |e-D conc=0.1 | ||
|solvent A=Molecule:100529 | |solvent A=Molecule:100529 | ||
|feedstock gas=CO2 | |||
|λexc=> 435 | |λexc=> 435 | ||
|irr time=47 | |irr time=47 | ||
| Line 24: | Line 25: | ||
|additives=TFE | |additives=TFE | ||
|additives conc=0.1 | |additives conc=0.1 | ||
|feedstock gas=CO2 | |||
|λexc=> 435 | |λexc=> 435 | ||
|irr time=47 | |irr time=47 | ||
|TON CO=71 | |TON CO=71 | ||
|TON CH4=14 | |TON CH4=14 | ||
|TON H2= | |TON H2=10 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
| Line 40: | Line 42: | ||
|additives=TFE | |additives=TFE | ||
|additives conc=0.1 | |additives conc=0.1 | ||
|feedstock gas=CO2 | |||
|λexc=> 435 | |λexc=> 435 | ||
|irr time=102 | |irr time=102 | ||
Latest revision as of 10:59, 26 February 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.01 | 1 | 0.1 |
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CO2 | > 435 | 47 | 50 | 8 | 8 | 75.8%; 12.1%; 12.1%; 0%; 0% |
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Yes | |||||||||||||||||||||||||
| 0.01 | 1 | 0.1 |
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TFE | 0.1 | CO2 | > 435 | 47 | 71 | 14 | 10 | 74.7%; 14.7%; 10.5%; 0%; 0% |
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Yes | |||||||||||||||||||||||
| 0.01 | 1 | 0.1 |
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|
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TFE | 0.1 | CO2 | > 435 | 102 | 140 | 29 | 23 | 72.9%; 15.1%; 12.0%; 0%; 0% |
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Yes |
