Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst/Photocatalytic reduction of CO2: Difference between revisions
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|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
| Line 8: | Line 8: | ||
|e-D conc=0.1 | |e-D conc=0.1 | ||
|solvent A=Molecule:100529 | |solvent A=Molecule:100529 | ||
|feedstock gas=CO2 | |||
|λexc=> 435 | |λexc=> 435 | ||
|irr time=47 | |irr time=47 | ||
| | |Turnover_number__CO=50 | ||
| | |Turnover_number__CH4=8 | ||
| | |Turnover_number__H2=8 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
| Line 24: | Line 25: | ||
|additives=TFE | |additives=TFE | ||
|additives conc=0.1 | |additives conc=0.1 | ||
|feedstock gas=CO2 | |||
|λexc=> 435 | |λexc=> 435 | ||
|irr time=47 | |irr time=47 | ||
| | |Turnover_number__CO=71 | ||
| | |Turnover_number__CH4=14 | ||
| | |Turnover_number__H2=10 | ||
|include=Yes | |include=Yes | ||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100826 | |catalyst=Molecule:100826 | ||
|cat conc= | |cat conc=10 | ||
|PS=Molecule:100493 | |PS=Molecule:100493 | ||
|PS conc=1 | |PS conc=1 | ||
| Line 40: | Line 42: | ||
|additives=TFE | |additives=TFE | ||
|additives conc=0.1 | |additives conc=0.1 | ||
|feedstock gas=CO2 | |||
|λexc=> 435 | |λexc=> 435 | ||
|irr time=102 | |irr time=102 | ||
| | |Turnover_number__CO=140 | ||
| | |Turnover_number__CH4=29 | ||
| | |Turnover_number__H2=23 | ||
|include=Yes | |include=Yes | ||
}} | }} | ||
}} | }} | ||
Latest revision as of 13:33, 29 January 2026
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume [mL] | intensity [kW/m²] | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO [TOF/min] | Φ CO [%] | TON CH4 | TOF CH4 [TOF/min] | Φ CH4 [%] | TON H2 | TOF H2 [TOF/min] | Φ H2 [%] | TON HCOOH | TOF HCOOH [TOF/min] | Φ HCOOH [%] | TON MeOH | TOF MeOH [TOF/min] | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 10 | 1 | 0.1 |
|
|
|
CO2 | > 435 | 47 | 50 | 8 | 8 | 75.8%; 12.1%; 12.1%; 0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.1 | CO2 | > 435 | 47 | 71 | 14 | 10 | 74.7%; 14.7%; 10.5%; 0%; 0% |
|
Yes | ||||||||||||||||||||||||
| 10 | 1 | 0.1 |
|
|
|
TFE | 0.1 | CO2 | > 435 | 102 | 140 | 29 | 23 | 72.9%; 15.1%; 12.0%; 0%; 0% |
|
Yes |
