Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex/Photoreduction of CO2 result: Difference between revisions

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< Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex
investigation
Molecular process, Photocatalytic CO2 conversion experiments
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Line 3: Line 3:
|catalyst=Molecule:100813
|catalyst=Molecule:100813
|cat conc=0.03
|cat conc=0.03
|solvent A=Molecule:100616
|e-D=Molecule:100861
|additives=ascorbate
|e-D conc=0.1
|additives conc=0.1
|solvent A=Molecule:100530
|solvent B=Molecule:100616
|pH=6.5
|pH=6.5
|λexc=450
|λexc=450

Latest revision as of 17:10, 29 January 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[Ni(cyclam-trzbpy)Ru(bpy)2][PF6]4

0.03


Molecule:100861

0.1


MeCN

H2O


6.5 450 60 5.2 2 72.2%; 0%; 27.8%; 0%; 0%


No