Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production/Table 1

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1			DMA	H2O		9:1							25	450	55	713		1.42				6.9									99.0%; 0%; 1.0%; 0%; 0%	1.42		Yes
[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1			DMF	H2O		9:1							25	450		159						11									93.5%; 0%; 6.5%; 0%; 0%			Yes
[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1			DMA	H2O		9:1							25	450		67						3.4									95.2%; 0%; 4.8%; 0%; 0%			Yes
[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	BIH	0.1			MeCN	H2O		9:1							25	450																	n/a			No
[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	TEA	0.1			DMA	H2O		9:1							25	450																	n/a			No
[Ni(bpet)(MeCN)2][ClO4]2	0.03	Ru(bpy)3Cl2	0.5	TEOA	0.1			DMA	H2O		9:1							25	450		2.6						25.5									9.3%; 0%; 90.7%; 0%; 0%			Yes