Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer/Visible-Light Driven CO2 Reduction with 1/TATA+/BIH + TEOA under Various Conditions

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1			MeCN	TEOA		85/15								450		2332						106			1370						61.2%; 0%; 2.8%; 36.0%; 0%			No
		Molecule:100797	0.2	BIH	0.1			MeCN	TEOA		85/15								450		0						0			0						n/a			No
[Co(qpy)(H2O)2][ClO4]2	0.002			BIH	0.1			MeCN	TEOA		85/15								450		0						0			0						n/a			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2					MeCN	TEOA		85/15								450		950						86			316						70.3%; 0%; 6.4%; 23.4%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1			MeCN											450		107						7			5						89.9%; 0%; 5.9%; 4.2%; 0%			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1			MeCN	TEOA		85/15	Argon atmosphere							450		0						7			0						n/a			No
CoCl2	0.005	Molecule:100797	0.2	BIH	0.1			MeCN	TEOA		85/15								450		0						159			0						n/a			No
[Co(qpy)(H2O)2][ClO4]2	0.002	Molecule:100797	0.2	BIH	0.1			MeCN	TEOA		85/15	Hg (0.1 mL)							450		1880						255			1973						45.8%; 0%; 6.2%; 48.0%; 0%			No