Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes/Optimizations of conditions for Co(qpy)(H2O)2(ClO4)2 and Ru(bpy)3Cl2: Difference between revisions
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< Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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| Line 13: | Line 13: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=2660 | |TON CO=2660 | ||
|TON H2=23 | |TON H2=23 | ||
|TON HCOOH=35 | |TON HCOOH=35 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0 | |cat conc=0 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 32: | Line 29: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=0 | |TON CO=0 | ||
|TON H2=2 | |TON H2=2 | ||
|TON HCOOH=1 | |TON HCOOH=1 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.005 | |cat conc=0.005 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 52: | Line 46: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=0 | |TON CO=0 | ||
|TON H2=33 | |TON H2=33 | ||
|TON HCOOH=0 | |TON HCOOH=0 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.005 | |cat conc=0.005 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 69: | Line 60: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=182 | |TON CO=182 | ||
|TON H2=0 | |TON H2=0 | ||
|TON HCOOH=11 | |TON HCOOH=11 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.005 | |cat conc=0.005 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 86: | Line 74: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=114 | |TON CO=114 | ||
|TON H2=25 | |TON H2=25 | ||
|TON HCOOH=25 | |TON HCOOH=25 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.01 | |cat conc=0.01 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 105: | Line 90: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=1875 | |TON CO=1875 | ||
|TON H2=11 | |TON H2=11 | ||
|TON HCOOH=18 | |TON HCOOH=18 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.2 | |cat conc=0.2 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 124: | Line 106: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=1262 | |TON CO=1262 | ||
|TON H2=7 | |TON H2=7 | ||
|TON HCOOH=23 | |TON HCOOH=23 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 143: | Line 122: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=497 | |TON CO=497 | ||
|TON H2=5 | |TON H2=5 | ||
|TON HCOOH=3 | |TON HCOOH=3 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 160: | Line 136: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=0 | |TON CO=0 | ||
|TON H2=1 | |TON H2=1 | ||
|TON HCOOH=1 | |TON HCOOH=1 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.1 | |cat conc=0.1 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 179: | Line 152: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=466 | |TON CO=466 | ||
|TON H2=2 | |TON H2=2 | ||
|TON HCOOH=22 | |TON HCOOH=22 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 198: | Line 168: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=521 | |TON CO=521 | ||
|TON H2=49 | |TON H2=49 | ||
|TON HCOOH=6 | |TON HCOOH=6 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0 | |cat conc=0 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 217: | Line 184: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=136 | |TON CO=136 | ||
|TON H2=43 | |TON H2=43 | ||
|TON HCOOH=5 | |TON HCOOH=5 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 236: | Line 200: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=366 | |TON CO=366 | ||
|TON H2=15 | |TON H2=15 | ||
|TON HCOOH=4 | |TON HCOOH=4 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0.05 | |cat conc=0.05 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 256: | Line 217: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=0 | |TON CO=0 | ||
|TON H2=3 | |TON H2=3 | ||
|TON HCOOH=1 | |TON HCOOH=1 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100788 | ||
|cat conc=0 | |cat conc=0 | ||
|PS=Molecule:100787 | |PS=Molecule:100787 | ||
| Line 275: | Line 233: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=0 | |TON CO=0 | ||
|TON H2=6 | |TON H2=6 | ||
|TON HCOOH=1 | |TON HCOOH=1 | ||
|include=Yes | |||
|include= | |||
}}{{Photocatalytic CO2 conversion | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100789 | |catalyst=Molecule:100789 | ||
| Line 294: | Line 249: | ||
|irr time=1.33 | |irr time=1.33 | ||
|TON CO=33 | |TON CO=33 | ||
|TON H2=11 | |TON H2=11 | ||
|TON HCOOH=1 | |TON HCOOH=1 | ||
| | |include=Yes | ||
|include= | }}{{Photocatalytic CO2 conversion | ||
|catalyst=Molecule:100788 | |||
|cat conc=0.05 | |||
|PS=Molecule:100787 | |||
|PS conc=0.3 | |||
|H-D=Molecule:100507 | |||
|H-D conc=0.5 | |||
|solvent A=Molecule:100530 | |||
|λexc=460 (LED) | |||
|irr time=1.33 | |||
|TON CO=0 | |||
|TON H2=1 | |||
|TON HCOOH=1 | |||
|include=Yes | |||
}} | }} | ||
}} | }} | ||
Latest revision as of 15:38, 17 May 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.005 | 0.3 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 2660 | 23 | 35 | 97.9%; 0%; 0.8%; 1.3%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0 | 0.3 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 0 | 2 | 1 | 0%; 0%; 66.7%; 33.3%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.005 | 0.3 | 0.1 | 0.5 |
|
|
Argon atmosphere | 460 (LED) | 1.33 | 0 | 33 | 0 | n/a |
|
Yes | |||||||||||||||||||||||||
| 0.005 | 0.3 | 0.1 |
|
|
|
460 (LED) | 1.33 | 182 | 0 | 11 | 94.3%; 0%; 0%; 5.7%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.005 | 0.3 |
|
0.5 |
|
|
460 (LED) | 1.33 | 114 | 25 | 25 | 69.5%; 0%; 15.2%; 15.2%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.01 | 0.3 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 1875 | 11 | 18 | 98.5%; 0%; 0.6%; 0.9%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.2 | 0.3 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 1262 | 7 | 23 | 97.7%; 0%; 0.5%; 1.8%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.3 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 497 | 5 | 3 | 98.4%; 0%; 1.0%; 0.6%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.3 |
|
0.5 |
|
|
460 (LED) | 1.33 | 0 | 1 | 1 | 0%; 0%; 50.0%; 50.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.1 | 0.3 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 466 | 2 | 22 | 95.1%; 0%; 0.4%; 4.5%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.5 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 521 | 49 | 6 | 90.5%; 0%; 8.5%; 1.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0 | 0.5 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 136 | 43 | 5 | 73.9%; 0%; 23.4%; 2.7%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.2 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 366 | 15 | 4 | 95.1%; 0%; 3.9%; 1.0%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.2 | 0.1 | 0.5 |
|
|
Argon atmosphere | 460 (LED) | 1.33 | 0 | 3 | 1 | 0%; 0%; 75.0%; 25.0%; 0% |
|
Yes | |||||||||||||||||||||||||
| 0 | 0.2 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 0 | 6 | 1 | 0%; 0%; 85.7%; 14.3%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.3 | 0.1 | 0.5 |
|
|
460 (LED) | 1.33 | 33 | 11 | 1 | 73.3%; 0%; 24.4%; 2.2%; 0% |
|
Yes | ||||||||||||||||||||||||||
| 0.05 | 0.3 |
|
0.5 |
|
|
460 (LED) | 1.33 | 0 | 1 | 1 | 0%; 0%; 50.0%; 50.0%; 0% |
|
Yes |
