Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light/Table 2: Difference between revisions

From ChemWiki
< Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light
investigation
Molecular process, Photocatalytic CO2 conversion experiments
No edit summary
No edit summary
 
(4 intermediate revisions by the same user not shown)
Line 1: Line 1:
{{Photocatalytic CO2 conversion experiments
{{Photocatalytic CO2 conversion experiments
|experiments={{Photocatalytic CO2 conversion
|experiments={{Photocatalytic CO2 conversion
|catalyst=Molecule:100610
|catalyst=Molecule:100854
|cat conc=0.0062
|cat conc=0.0062
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 16: Line 16:
|catalyst=Molecule:100482
|catalyst=Molecule:100482
|cat conc=0.0062
|cat conc=0.0062
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 27: Line 27:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100611
|catalyst=Molecule:100840
|cat conc=0.0062
|cat conc=0.0062
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 40: Line 40:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100612
|catalyst=Molecule:100838
|cat conc=0.0062
|cat conc=0.0062
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 53: Line 53:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100782
|catalyst=Molecule:100836
|cat conc=0.0062
|cat conc=0.0062
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 66: Line 66:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100609
|catalyst=Molecule:100888
|cat conc=0.0062
|cat conc=0.0062
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 79: Line 79:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100611
|catalyst=Molecule:100840
|cat conc=0.0031
|cat conc=0.0031
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 92: Line 92:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100612
|catalyst=Molecule:100838
|cat conc=0.0031
|cat conc=0.0031
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 105: Line 105:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100782
|catalyst=Molecule:100836
|cat conc=0.0031
|cat conc=0.0031
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 118: Line 118:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100611
|catalyst=Molecule:100840
|cat conc=0.0016
|cat conc=0.0016
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 131: Line 131:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100612
|catalyst=Molecule:100838
|cat conc=0.0016
|cat conc=0.0016
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 144: Line 144:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100782
|catalyst=Molecule:100836
|cat conc=0.0016
|cat conc=0.0016
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507
Line 157: Line 157:
|include=Yes
|include=Yes
}}{{Photocatalytic CO2 conversion
}}{{Photocatalytic CO2 conversion
|catalyst=Molecule:100609
|catalyst=Molecule:100888
|cat conc=0.0016
|cat conc=0.0016
|PS=Molecule:100487
|PS=Molecule:100784
|PS conc=0.025
|PS conc=0.025
|e-D=Molecule:100507
|e-D=Molecule:100507

Latest revision as of 13:02, 26 February 2024

cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Ru(bpy)2Cl2

0.0062

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 3 9 26 7.9%; 0%; 23.7%; 68.4%; 0%


Yes

Ru(bpy)2CO3

0.0062

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 3 11 39 5.7%; 0%; 20.8%; 73.6%; 0%


Yes

[Ru(bpy)2ClCO][PF6]

0.0062

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 19 19 117 12.3%; 0%; 12.3%; 75.5%; 0%


Yes

[Ru(bpy)2HCO][PF6]

0.0062

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 21 16 107 14.6%; 0%; 11.1%; 74.3%; 0%


Yes

[Ru(bpy)(H2O)(CO)][PF6]

0.0062

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 21 14 75 19.1%; 0%; 12.7%; 68.2%; 0%


Yes

[Ru(bpy)(AcMe)2][PF6]

0.0062

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 4 12 64 5.0%; 0%; 15.0%; 80.0%; 0%


Yes

[Ru(bpy)2ClCO][PF6]

0.0031

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 36 33 296 9.9%; 0%; 9.0%; 81.1%; 0%


Yes

[Ru(bpy)2HCO][PF6]

0.0031

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 16 29 145 8.4%; 0%; 15.3%; 76.3%; 0%


Yes

[Ru(bpy)(H2O)(CO)][PF6]

0.0031

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 34 28 211 12.5%; 0%; 10.3%; 77.3%; 0%


Yes

[Ru(bpy)2ClCO][PF6]

0.0016

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 40 67 419 7.6%; 0%; 12.7%; 79.7%; 0%


Yes

[Ru(bpy)2HCO][PF6]

0.0016

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 25 62 225 8.0%; 0%; 19.9%; 72.1%; 0%


Yes

[Ru(bpy)(H2O)(CO)][PF6]

0.0016

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 45 65 335 10.1%; 0%; 14.6%; 75.3%; 0%


Yes

[Ru(bpy)(AcMe)2][PF6]

0.0016

[Ir(ppy)2(bpy)][PF6]

0.025

TEOA


NMP



25 400 - 700 4 44 75 3.3%; 0%; 35.8%; 61.0%; 0%


Yes
Retrieved from "https://chemwiki.scc.kit.edu/main/mediawiki/index.php?title=Photochemical_Reduction_of_Carbon_Dioxide_to_Formic_Acid_using_Ruthenium(II)-Based_Catalysts_and_Visible_Light/Table_2&oldid=6890"
Powered by MediaWiki
Powered by Semantic MediaWiki