Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light/Table 3 - CV: Difference between revisions

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{{Cyclic Voltammetry experiments
{{Cyclic Voltammetry experiments
|experiments={{Cyclic Voltammetry
|experiments={{Cyclic Voltammetry
|anl=Molecule:100610
|anl=Molecule:100854
|redox potential=0,-2.11
|redox potential=0,-2.11
|solv=Molecule:100530
|solv=Molecule:100530
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|anl=Molecule:100482
|anl=Molecule:100482
|redox potential=0.45,-1.97
|redox potential=0.45,-1.97
|solv=Molecule:100530
|electrolyte=TBABF4
|el conc=0.1
|scan rate=100
|WE=glassy carbon
|WE area=0.79
|CE=platinum
|RE=Ag/AgNO3 in MeCN
|include=Yes
}}{{Cyclic Voltammetry
|anl=Molecule:100840
|redox potential=1.22,-1.75
|solv=Molecule:100530
|electrolyte=TBABF4
|el conc=0.1
|scan rate=100
|WE=glassy carbon
|WE area=0.79
|CE=platinum
|RE=Ag/AgNO3 in MeCN
|include=Yes
}}{{Cyclic Voltammetry
|anl=Molecule:100838
|redox potential=1.20,-1.61
|solv=Molecule:100530
|solv=Molecule:100530
|electrolyte=TBABF4
|electrolyte=TBABF4

Latest revision as of 12:20, 12 January 2024

analyte anl conc [mM] reduction potential oxidation potential solvent solvent vol [ml] electrolyte electrolyte purity el conc [M] int ref comp scan rate [mv s-1] scan number potential window scan dir gas T [° C] condition [nm] WE WE surface area [mm²] CE RE Details include

Ru(bpy)2Cl2

0,-2.11

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes

Ru(bpy)2CO3

0.45,-1.97

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes

[Ru(bpy)2ClCO][PF6]

1.22,-1.75

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes

[Ru(bpy)2HCO][PF6]

1.20,-1.61

MeCN

TBABF4

0.1


100 glassy carbon 0.79 platinum Ag/AgNO3 in MeCN Yes