Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex/Photoreduction of CO2 result: Difference between revisions
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< Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
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{{Photocatalytic CO2 conversion experiments | {{Photocatalytic CO2 conversion experiments | ||
|experiments={{Photocatalytic CO2 conversion | |experiments={{Photocatalytic CO2 conversion | ||
|catalyst=Molecule: | |catalyst=Molecule:100813 | ||
|cat conc=0.03 | |cat conc=0.03 | ||
| | |e-D=Molecule:100861 | ||
|e-D conc=0.1 | |||
| | |solvent A=Molecule:100530 | ||
|solvent B=Molecule:100616 | |||
|pH=6.5 | |pH=6.5 | ||
|λexc=450 | |λexc=450 | ||
Latest revision as of 17:10, 29 January 2024
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.03 |
|
0.1 |
|
|
6.5 | 450 | 60 | 5.2 | 2 | 72.2%; 0%; 27.8%; 0%; 0% |
|
No |
