Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

Latest revision as of 21:40, 6 August 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solv A/B/C	additives	feedstock gas	intensity [kW/m²]	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON CH4	TON H2	TOF H2 [TOF/min]	TON HCOOH	TOF HCOOH [TOF/min]	Φ HCOOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]
Fe1	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	987	41.1	not reported	not reported	187	not reported	not reported	not reported	not reported	84.1%; 0%; 15.9%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	1318	54.9	not reported	not reported	243	not reported	not reported	not reported	not reported	84.4%; 0%; 15.6%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe3	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	847	35.3	not reported	not reported	205	not reported	not reported	not reported	not reported	80.5%; 0%; 19.5%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe4	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	1265	52.7	not reported	not reported	133	not reported	not reported	not reported	not reported	90.5%; 0%; 9.5%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	4	311	77.7	not reported	not reported	51	not reported	not reported	not reported	not reported	85.9%; 0%; 14.1%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	48	1578	32.9	not reported	not reported	296	not reported	not reported	not reported	not reported	84.2%; 0%; 15.8%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	96	1593	16.6	not reported	not reported	300	not reported	not reported	not reported	not reported	84.2%; 0%; 15.8%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	0 v/v	35	not reported	not reported	308 K	462	24	2	not reported	not reported	not reported	22	not reported	not reported	not reported	not reported	8.3%; 0%; 91.7%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	10 v/v	35	not reported	not reported	308 K	462	24	1352	56.3	not reported	not reported	285	not reported	not reported	not reported	not reported	82.6%; 0%; 17.4%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	30 v/v	35	not reported	not reported	308 K	462	24	661	27.5	not reported	not reported	191	not reported	not reported	not reported	not reported	77.6%; 0%; 22.4%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	50.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	50 v/v	35	not reported	not reported	308 K	462	24	621	25.8	not reported	not reported	77	not reported	not reported	not reported	not reported	89.0%; 0%; 11.0%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	25.0	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	2086	86.9	not reported	not reported	123	not reported	not reported	not reported	not reported	94.4%; 0%; 5.6%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	12.5	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	4259	177.4	not reported	not reported	276	not reported	not reported	not reported	not reported	93.9%; 0%; 6.1%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	6.25	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	10168	423.7	not reported	not reported	862	not reported	not reported	not reported	not reported	92.2%; 0%; 7.8%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	3.12	［Ru(bpy)3］2+	0.3	BIH	0.11	not reported	Molecule:100616	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	24	23138	964.1	not reported	not reported	2177	not reported	not reported	not reported	not reported	91.4%; 0%; 8.6%; 0%; 0%		<ul><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"not reported" is not a number.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>
Fe2	3.12	［Ru(bpy)3］2+	0.3	BIH	0.11	H2O	not reported	MeCN	H2O	CO2	7.5 v/v	35	not reported	not reported	308 K	462	4	9754	2438	8.24	not reported	not reported	not reported	not reported	not reported	not reported	n/a	8.24	<ul><li>"not reported" is not a number.</li> <!--br--><li>"35" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"K" can not be assigned to a declared number type with value 308.</li></ul>

@@ Line 1: / Line 1: @@
 {{Photocatalytic_CO2_conversion_experiments|experiments={{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzphen)(H2O)2](BF4)2 (Fe1)
+|catalyst=Fe1
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=987
-|Turnover_frequency__CO=41.1 h−1
+|Turnover_frequency__CO=41.1
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=187
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=1318
-|Turnover_frequency__CO=54.9 h−1
+|Turnover_frequency__CO=54.9
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=243
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)
+|catalyst=Fe3
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=847
-|Turnover_frequency__CO=35.3 h−1
+|Turnover_frequency__CO=35.3
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=205
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)
+|catalyst=Fe4
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=1265
-|Turnover_frequency__CO=52.7 h−1
+|Turnover_frequency__CO=52.7
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=133
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=4 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=4
 |Turnover_number__CO=311
-|Turnover_frequency__CO=77.7 h−1
+|Turnover_frequency__CO=77.7
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=51
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=48 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=48
 |Turnover_number__CO=1578
-|Turnover_frequency__CO=32.9 h−1
+|Turnover_frequency__CO=32.9
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=296
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=96 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=96
 |Turnover_number__CO=1593
-|Turnover_frequency__CO=16.6 h−1
+|Turnover_frequency__CO=16.6
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=300
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
-|solvent B=
+|solvent B=Molecule:100616
-|solvent-ratio=
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=0 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=2
-|Turnover_frequency__CO=< 0.1 h−1
+|Turnover_frequency__CO=not reported
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=22
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=10% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=10 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=1352
-|Turnover_frequency__CO=56.3 h−1
+|Turnover_frequency__CO=56.3
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=285
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=30% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=30 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=661
-|Turnover_frequency__CO=27.5 h−1
+|Turnover_frequency__CO=27.5
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=191
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=50.0 μM
+|cat conc=50.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=50% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=50 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=621
-|Turnover_frequency__CO=25.8 h−1
+|Turnover_frequency__CO=25.8
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=77
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=25.0 μM
+|cat conc=25.0
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=2086
-|Turnover_frequency__CO=86.9 h−1
+|Turnover_frequency__CO=86.9
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=123
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=12.5 μM
+|cat conc=12.5
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent C=
-|feedstock gas=CO2-saturated
+|solvent-ratio=CO2
-|Temperature=35 °C
+|additives=7.5 v/v
-|λexc=462 nm (blue LED strip)
+|additives conc=
-|irr time=24 h
+|feedstock gas=35
+|intensity=not reported
+|pH=not reported
+|Temperature=308 K
+|λexc=462
+|irr time=24
 |Turnover_number__CO=4259
-|Turnover_frequency__CO=177.4 h−1
+|Turnover_frequency__CO=177.4
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
 |Turnover_number__H2=276
-|Turnover_frequency__H2=
+|Turnover_frequency__H2=not reported
-|additives=
+|Turnover_number__HCOOH=not reported
-|Turnover_number__HCOOH=
+|Turnover_frequency__HCOOH=not reported
-|intensity=
+|Quantum_yield__HCOOH=not reported
-|Turnover_number__CH4=
+|H-D=not reported
-|additives conc=
+|H-D conc=Molecule:100616
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|catalyst=Fe2
-|cat conc=6.25 μM
+|cat conc=6.25
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm (blue LED strip)
-|irr time=24 h
-|Turnover_number__CO=10
-|Turnover_frequency__CO=168
-|Turnover_number__H2=423.7 h−1
-|Turnover_frequency__H2=862
-|additives=
-|Turnover_number__HCOOH=
-|intensity=
-|Turnover_number__CH4=
-|additives conc=
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
 |solvent C=
-|Quantum_yield__HCOOH=
+|solvent-ratio=CO2
-|pH=
+|additives=7.5 v/v
-|Turnover_frequency__HCOOH=
-}}
-{{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=3.12 μM
-|PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
-|e-D=Molecule:100508
-|e-D conc=0.11 M
-|solvent A=Molecule:100530
-|solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm (blue LED strip)
-|irr time=24 h
-|Turnover_number__CO=23
-|Turnover_frequency__CO=138
-|Turnover_number__H2=964.1 h−1
-|Turnover_frequency__H2=2177
-|additives=
-|Turnover_number__HCOOH=
-|intensity=
-|Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=
+|feedstock gas=35
-|H-D=
+|intensity=not reported
-|H-D conc=
+|pH=not reported
-|solvent C=
+|Temperature=308 K
-|Quantum_yield__HCOOH=
+|λexc=462
-|pH=
+|irr time=24
-|Turnover_frequency__HCOOH=
+|Turnover_number__CO=10168
+|Turnover_frequency__CO=423.7
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
+|Turnover_number__H2=862
+|Turnover_frequency__H2=not reported
+|Turnover_number__HCOOH=not reported
+|Turnover_frequency__HCOOH=not reported
+|Quantum_yield__HCOOH=not reported
+|H-D=not reported
+|H-D conc=Molecule:100616
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzphen)(H2O)2](BF4)2 (Fe1)
+|catalyst=Fe2
-|cat conc=3.25 μM
+|cat conc=3.12
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm
-|irr time=4 h
-|Turnover_number__CO=
-|Turnover_frequency__CO=
-|Turnover_number__H2=
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
-|Turnover_number__CH4=
-|additives conc=
-|Quantum_yield__CO=4.8%
-|H-D=
-|H-D conc=
 |solvent C=
-|Quantum_yield__HCOOH=
+|solvent-ratio=CO2
-|pH=
+|additives=7.5 v/v
-|Turnover_frequency__HCOOH=
-}}
-{{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=3.25 μM
-|PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
-|e-D=Molecule:100508
-|e-D conc=0.11 M
-|solvent A=Molecule:100530
-|solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm
-|irr time=4 h
-|Turnover_number__CO=9754
-|Turnover_frequency__CO=2438 h−1
-|Turnover_number__H2=
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
-|Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=7.6%
+|feedstock gas=35
-|H-D=
+|intensity=not reported
-|H-D conc=
+|pH=not reported
-|solvent C=
+|Temperature=308 K
-|Quantum_yield__HCOOH=
+|λexc=462
-|pH=
+|irr time=24
-|Turnover_frequency__HCOOH=
+|Turnover_number__CO=23138
+|Turnover_frequency__CO=964.1
+|Quantum_yield__CO=not reported
+|Turnover_number__CH4=not reported
+|Turnover_number__H2=2177
+|Turnover_frequency__H2=not reported
+|Turnover_number__HCOOH=not reported
+|Turnover_frequency__HCOOH=not reported
+|Quantum_yield__HCOOH=not reported
+|H-D=not reported
+|H-D conc=Molecule:100616
 }}
 {{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)
+|catalyst=Fe2
-|cat conc=3.25 μM
+|cat conc=3.12
 |PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
+|PS conc=0.3
 |e-D=Molecule:100508
-|e-D conc=0.11 M
+|e-D conc=0.11
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm
-|irr time=4 h
-|Turnover_number__CO=
-|Turnover_frequency__CO=
-|Turnover_number__H2=
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
-|Turnover_number__CH4=
-|additives conc=
-|Quantum_yield__CO=3.8%
-|H-D=
-|H-D conc=
 |solvent C=
-|Quantum_yield__HCOOH=
+|solvent-ratio=CO2
-|pH=
+|additives=7.5 v/v
-|Turnover_frequency__HCOOH=
-}}
-{{Photocatalytic_CO2_conversion
-|catalyst=[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)
-|cat conc=3.25 μM
-|PS=[Ru(bpy)3]2+
-|PS conc=0.3 mM
-|e-D=Molecule:100508
-|e-D conc=0.11 M
-|solvent A=Molecule:100530
-|solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm
-|irr time=4 h
-|Turnover_number__CO=
-|Turnover_frequency__CO=
-|Turnover_number__H2=
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
-|Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=7.2%
+|feedstock gas=35
-|H-D=
+|intensity=not reported
-|H-D conc=
+|pH=not reported
-|solvent C=
+|Temperature=308 K
-|Quantum_yield__HCOOH=
+|λexc=462
-|pH=
+|irr time=4
-|Turnover_frequency__HCOOH=
+|Turnover_number__CO=9754
-}}
+|Turnover_frequency__CO=2438
-{{Photocatalytic_CO2_conversion
+|Quantum_yield__CO=8.24
-|catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
+|Turnover_number__CH4=not reported
-|cat conc=50 μM
+|Turnover_number__H2=not reported
-|PS=[Ru(bpy)3]2+
+|Turnover_frequency__H2=not reported
-|PS conc=0.3 mM
+|Turnover_number__HCOOH=not reported
-|e-D=Molecule:100508
+|Turnover_frequency__HCOOH=not reported
-|e-D conc=27.5 mM
+|Quantum_yield__HCOOH=not reported
-|solvent A=Molecule:100530
+|H-D=Molecule:100616
-|solvent B=Molecule:100616
+|H-D conc=not reported
-|solvent-ratio=7.5% H2O (v/v)
-|feedstock gas=CO2-saturated
-|Temperature=35 °C
-|λexc=462 nm (blue LED strip)
-|irr time=24 h
-|Turnover_number__CO=221
-|Turnover_frequency__CO=
-|Turnover_number__H2=
-|Turnover_frequency__H2=
-|additives=
-|Turnover_number__HCOOH=
-|intensity=
-|Turnover_number__CH4=
-|additives conc=
-|Quantum_yield__CO=
-|H-D=
-|H-D conc=
-|solvent C=
-|Quantum_yield__HCOOH=
-|pH=
-|Turnover_frequency__HCOOH=
 }}
 }}

Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

Latest revision as of 21:40, 6 August 2026

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