Electrocatalytic Reduction of CO2 to Ethylene by Molecular Cu-Complex Immobilized on Graphitized Mesoporous Carbon/Bulk Electrolysis: Difference between revisions
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|experiments={{EC conversion of CO2 | |experiments={{EC conversion of CO2 | ||
|experiment_type=experimental | |experiment_type=experimental | ||
|catalyst= | |catalyst=Molecule:101025 | ||
|cat carrier=graphitized mesoporous carbon (GMC) | |cat carrier=graphitized mesoporous carbon (GMC) | ||
|supporting_electrolyte__WE=KCl | |||
|supporting_electrolyte_concentration__WE=0.1 | |||
|supporting_electrolyte__CE=KCl | |||
|supporting_electrolyte_concentration__CE=0.1 | |||
|cathodic potential=-1.278 | |cathodic potential=-1.278 | ||
|faradaic_efficiency__HCOOH=10 | |||
|faradaic_efficiency__H2=28 | |||
|faradaic_efficiency__CH4=20 | |||
|faradaic_efficiency__C2H4=42 | |faradaic_efficiency__C2H4=42 | ||
|include=Yes | |include=Yes | ||
}} | }} | ||
}} | }} | ||
Latest revision as of 16:47, 1 April 2026
| experiment type | catalyst | cat conc [µM] | immobilization technique | catalyst carrier material | cell type | separator | working electrode (WE) | counter electrode (CE) | reference electrode (WE) | solvent A (WE) | solvent B (WE) | solvent C (WE) | solvent ratio (WE) | additives (WE) | additives concentration (WE) [M] | buffer (WE) | buffer concentration (WE) [M] | supporting electrolyte (WE) | supporting_electrolyte concentration (WE) [M] | solvent A (CE) | solvent B (CE) | solvent C (CE) | solvent ratio (CE) | additives (CE) | additives concentration (CE) [M] | buffer (CE) | buffer concentration (CE) [M] | supporting electrolyte (CE) | supporting_electrolyte concentration (CE) [M] | pH | current density [mA/cm²] | Cathodic potential vs RHE [V] | faradaic amount [F] | electrolysis duration [h] | limiting turnover number CO [Hz] | limiting turnover number HCOOH [Hz] | limiting turnover number H2C2O4 [Hz] | limiting turnover number H2CO [Hz] | limiting turnover number CH3OH [Hz] | limiting turnover number H2 [Hz] | limiting turnover number CH4 [Hz] | limiting turnover number C2H4 [Hz] | limiting turnover number CH3CH2OH [Hz] | maximum turnover frequency CO [Hz] | maximum turnover frequency HCOOH [Hz] | maximum turnover frequency H2C2O4 [Hz] | maximum turnover frequency H2CO [Hz] | maximum turnover frequency CH3OH [Hz] | maximum turnover frequency H2 [Hz] | maximum turnover frequency CH4 [Hz] | maximum turnover frequency C2H4 [Hz] | maximum turnover frequency CH3CH2OH [Hz] | turnover frequency at zero overpotential CO [Hz] | turnover frequency at zero overpotential HCOOH [Hz] | turnover frequency at zero overpotential H2C2O4 [Hz] | turnover frequency at zero overpotential H2CO [Hz] | turnover frequency at zero overpotential CH3OH [Hz] | turnover frequency at zero overpotential H2 [Hz] | turnover frequency at zero overpotential CH4 [Hz] | turnover frequency at zero overpotential C2H4 [Hz] | turnover frequency at zero overpotential CH3CH2OH [Hz] | faradaic efficiency CO [%] | faradaic efficiency HCOOH [%] | faradaic efficiency H2C2O4 [%] | faradaic efficiency H2CO [%] | faradaic efficiency CH3OH [%] | faradaic efficiency H2 [%] | faradaic efficiency CH4 [%] | faradaic efficiency C2H4 [%] | faradaic efficiency CH3CH2OH [%] | selectivity [%] [CO;HCOOH;H2C2O4;H2CO;CH3OH;H2;CH4;C2H4;CH3CH2OH] | total faradaic efficiency [%] | Details | include | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| experimental | graphitized mesoporous carbon (GMC) |
|
|
|
KCl | 0.1 |
|
|
|
KCl | 0.1 | -1.278 | 10 | 28 | 20 | 42 | n/a |
100 |
Yes |
