Category:Photocatalytic CO2 conversion to HCOOH: Difference between revisions

Revision as of 14:10, 18 October 2024

CO₂ conversion to formic acid[Pro21]

Formic acid (FA) is a simple chemical with many uses. Its applications include use as a preservative, in the leather and dyeing industry and chemical providing a C1 building block. It is also an important H₂ carrier, because of its qualities as non-toxic, easily storable liquid. This also makes it directly usable in fuel cells.[Fas16] The global production is currently estimated at 870.000 metric tons in 2021 with a CAGR (Compound Annual Growth Report) of 3.87% in volume terms during the period 2022-2027.[https://www.mordorintelligence.com/industry-reports/formic-acid-market]

Industrial production of formic acid is done mainly by carbonylation of methanol and subsequent hydrolysation of methyl formate to formic acid.[FA00]

A direct approach of synthesis by hydrogenation of CO₂ and using renewable energy, such as sunlight in photocatalysis, in a homogeneous environment, is the focus of this page.

Sacrificial electron donors

TEOA TEA BI(OH)H BIH BNAH

Ruthenium Catalysts

Ru(bpy)2CO3

Photosensitizers

Experiments

TON > 100

Cobalt Catalysts

Organic and semiconductor photosensitizer

3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine

Experiments

Literature

[Pro21] Photochemical reduction of carbon dioxide to formic acid. Robin Cauwenbergh, Shoubhik Das, Green Chemistry 2021, Vol. 23, Pages 2553-2574. DOI2: 10.1039/d0gc04040a

[Fas16] Formic acid synthesis using CO2 as raw material: Techno-economic and environmental evaluation and market potential. Mar Pérez-Fortes, Jan C. Schöneberger, Aikaterini Boulamanti, Gillian Harrison, Evangelos Tzimas, International Journal of Hydrogen Energy 2016, Vol. 41, Pages 16444-16462. DOI2: 10.1016/j.ijhydene.2016.05.199

[FA00] Formic Acid. Werner Reutemann, Heinz Kieczka, Ullmann's Encyclopedia of Industrial Chemistry 2000. DOI2: 10.1002/14356007.a12_013

[VLP20] Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate. Sung Eun Lee, Azam Nasirian, Ye Eun Kim, Pegah Tavakoli Fard, Youngmee Kim, Byeongmoon Jeong, Sung-Jin Kim, Jin-Ook Baeg, Jinheung Kim, Journal of the American Chemical Society 2020, Vol. 142, Pages 19142-19149. DOI2: 10.1021/jacs.0c08145
Publication: Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate

[PCR20] Photocatalytic CO ₂ Reduction under Visible‐Light Irradiation by Ruthenium CNC Pincer Complexes. Yasuhiro Arikawa, Itoe Tabata, Yukari Miura, Hiroki Tajiri, Yudai Seto, Shinnosuke Horiuchi, Eri Sakuda, Keisuke Umakoshi, Chemistry – A European Journal 2020, Vol. 26, Pages 5603-5606. DOI2: 10.1002/chem.201905840
Publication: Photocatalytic CO2 Reduction under Visible-Light Irradiation by Ruthenium CNC Pincer Complexes

[AiR19] An integrated Re(i) photocatalyst/sensitizer that activates the formation of formic acid from reduction of CO₂. Yasmeen Hameed, Patrick Berro, Bulat Gabidullin, Darrin Richeson, Chemical Communications 2019, Vol. 55, Pages 11041-11044. DOI2: 10.1039/c9cc03943k
Publication: An integrated Re(I) photocatalyst and sensitizer that activates the formation of formic acid from reduction of CO2

[PCR20] Photocatalytic CO₂ Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid. Kenji Kamada, Jieun Jung, Taku Wakabayashi, Keita Sekizawa, Shunsuke Sato, Takeshi Morikawa, Shunichi Fukuzumi, Susumu Saito, Journal of the American Chemical Society 2020, Vol. 142, Pages 10261-10266. DOI2: 10.1021/jacs.0c03097
Publication: Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid

[HEa16] Highly Efficient and Selective Photocatalytic CO₂ Reduction by Iron and Cobalt Quaterpyridine Complexes. Zhenguo Guo, Siwei Cheng, Claudio Cometto, Elodie Anxolabéhère-Mallart, Siu-Mui Ng, Chi-Chiu Ko, Guijian Liu, Lingjing Chen, Marc Robert, Tai-Chu Lau, Journal of the American Chemical Society 2016, Vol. 138, Pages 9413-9416. DOI2: 10.1021/jacs.6b06002
Publication: Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes

[PRo15] Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light. Alonso Rosas-Hernández, Henrik Junge, Matthias Beller, ChemCatChem 2015, Vol. 7, Pages 3316-3321. DOI2: 10.1002/cctc.201500494
Publication: Photochemical Reduction of Carbon Dioxide to Formic Acid using Ruthenium(II)-Based Catalysts and Visible Light

[VLP19] Visible‐Light Photocatalytic Reduction of CO ₂ to Formic Acid with a Ru Catalyst Supported by N , N ′‐Bis(diphenylphosphino)‐2,6‐diaminopyridine Ligands. Yasmeen Hameed, Gyandshwar Kumar Rao, Jeffrey S. Ovens, Bulat Gabidullin, Darrin Richeson, ChemSusChem 2019, Vol. 12, Pages 3453-3457. DOI2: 10.1002/cssc.201901326
Publication: Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands

[Rtr16] Rhenium(i) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO₂ reduction. Jana Rohacova, Osamu Ishitani, Chemical Science 2016, Vol. 7, Pages 6728-6739. DOI2: 10.1039/c6sc01913g
Publication: Rhenium(I) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction

[HEa18] Highly Efficient and Robust Photocatalytic Systems for CO₂ Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts. Hiroyuki Takeda, Hiroko Kamiyama, Kouhei Okamoto, Mina Irimajiri, Toshihide Mizutani, Kazuhide Koike, Akiko Sekine, Osamu Ishitani, Journal of the American Chemical Society 2018, Vol. 140, Pages 17241-17254. DOI2: 10.1021/jacs.8b10619
Publication: Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts

[PCr14] Photocatalytic CO₂reduction using a Mn complex as a catalyst. Hiroyuki Takeda, Hiroki Koizumi, Kouhei Okamoto, Osamu Ishitani, Chem. Commun. 2014, Vol. 50, Pages 1491-1493. DOI2: 10.1039/c3cc48122k
Publication: Photocatalytic CO2 reduction using a Mn complex as a catalyst

[PRo16] Photocatalytic Reduction of Carbon Dioxide to CO and HCO₂H Using fac-Mn(CN)(bpy)(CO)₃. Po Ling Cheung, Charles W. Machan, Aramice Y. S. Malkhasian, Jay Agarwal, Clifford P. Kubiak, Inorganic Chemistry 2016, Vol. 55, Pages 3192-3198. DOI2: 10.1021/acs.inorgchem.6b00379
Publication: Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3

@@ Line 290: / Line 290: @@
 == Experiments ==
+{{#experimentlink:%5B%5BTurnover%20number%20HCOOH%3A%3A%3E100%5D%5D|form=Photocatalytic_CO2_conversion_experiments|restrictToPages=|description=TON > 100|sort=Turnover number HCOOH, Catalyst|order=descending}}
 == Cobalt Catalysts ==

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	λexc [nm]	TON CO	TON H2	TON HCOOH	lit
1.	Ni(pbi)(pyS)2	4	Eosin Y	2	TEOA	0.4	H2O					14000	[VLP20]
2.	Ni(pbt)(pyS)2	4	Eosin Y	2	TEOA	0.4	H2O					13100	[VLP20]
3.	[Ru(bpy)(py)-(MeNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	300	1897	5634	[PCR20]
4.	[Ru(bpy)(py)-(MeNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	224	1438	4593	[PCR20]
5.	[Ru(bpy)(py)-(tBuNHC)2CO][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	129	505	3792	[PCR20]
6.	[Ru(bpy)(py)-(tBuNHC)2(MeCN)][PF6]2	0.01	[Ru(dmb)3][PF6]2	0.05	BI(OH)H	0.1	DMA		450 W Hg lamp, K2CrO4 filter	129	556	3296	[PCR20]
7.	[Re(bpy)2(CO)2][OTf]	10	[Ru(bpy)3][PF6]	1	TEOA		DMA		405		375	2750	[AiR19]
8.	[Ir(mesbpy-(PCy2)2)][BPh4]	20			BIH	0.2	DMA		>400	470	15	2080	[PCR20]
9.	[Re(bpy)2(CO)2][OTf]	20	[Ru(bpy)3][PF6]	1	TEOA		DMA		405		225	1480	[AiR19]
10.	[Re(bpy)2(CO)2][OTf]	50	[Ru(bpy)3][PF6]	1	TEOA		DMA		405		50	535	[AiR19]
11.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.2	BIH	0.1	MeCN		460 (LED)	3844	118	534	[HEa16]
12.	[Re(bpy)2(CO)2][OTf]	100	[Ru(bpy)3][PF6]	1	TEOA		DMA		405		38	428	[AiR19]
13.	[Ru(bpy)2ClCO][PF6]	0.002	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	40	67	419	[PRo15]
14.	[Ru(bpy)2ClCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	40	67	419	[PRo15]
15.	Ru(py)-(MeNdpp)2(CO)2Cl	25	[Ru(bpy)3][PF6]	0.025	TEOA		DMF		405			380	[VLP19]
16.	Ru(py)-(MeNdpp)2(CO)2Cl	100	[Ru(bpy)3][PF6]	0.1	TEOA		DMF		405		57.5	363	[VLP19]
17.	[Ru(bpy)(H2O)(CO)][PF6]	0.002	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	45	65	335	[PRo15]
18.	[Ru(bpy)(H2O)(CO)][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	45	65	335	[PRo15]
19.	[Ru(bpy)2ClCO][PF6]	0.003	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	36	33	296	[PRo15]
20.	[Ru(bpy)2ClCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	36	33	296	[PRo15]
21.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05			DMF		436	20	72	290	[Rtr16]
22.	Ru(dtBubpy)(CO)2Cl2	50	Molecule:100877	0.05	BI(OH)H	0.03	DMF		436	16	49	280	[Rtr16]
23.	[Re(bpy)2(CO)2][OTf]	200	[Ru(bpy)3][PF6]	1	TEOA		DMA		405		24	275	[AiR19]
24.	[Ru(bpy)2HCO][PF6]	1.6	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	25	62	225	[PRo15]
25.	[Ru(bpy)2HCO][PF6]	0.002	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	25	62	225	[PRo15]
26.	[Ru(bpy)(H2O)(CO)][PF6]	0.003	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	34	28	211	[PRo15]
27.	[Ru(bpy)(H2O)(CO)][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	34	28	211	[PRo15]
28.	Ru(py)-(MeNdpp)2(CO)2Cl	50	[Ru(bpy)3][PF6]	0.05	TEOA		DMF		405			210	[VLP19]
29.	[Co(qpy)(H2O)2][ClO4]2	5	purpurin	2	BIH	0.1	DMF	Argon atmosphere	460 (LED)	0	226	167	[HEa16]
30.	Ru(py)-(MeNdpp)2(CO)2Cl	500	[Ru(bpy)3][PF6]	1	TEOA		DMF		405		14	162	[VLP19]
31.	Mn(bpy)(CO)3Br	50	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		436	50	4	157	[HEa18]
32.	Mn(bpy)(CO)3Br	50	Ru(bpy)3	0.05	BNAH	0.1	DMF		480	12	8	157	[PCr14]
33.	Mn(bpy)(CO)3Br	50	[Ru(dmb)3][PF6]2	0.05	BNAH	0.1	DMF		480	12	14	149	[PCr14]
34.	[Ru(bpy)2HCO][PF6]	3.1	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	16	29	145	[PRo15]
35.	[Ru(bpy)2HCO][PF6]	0.003	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	16	29	145	[PRo15]
36.	Mn(CN)(bpy)(CO)3	100	[Ru(dmb)3][PF6]2	0.5	BNAH	0.1	DMF		470	9.1	1.2	130	[PRo16]
37.	Mn(CN)(bpy)(CO)3	100	[Ru(dmb)3][PF6]2	1	BNAH	0.1	DMF		470	7.1	1.6	130	[PRo16]
38.	[Ru(bpy)2ClCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	19	19	117	[PRo15]
39.	[Ru(bpy)2ClCO][PF6]	0.006	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	19	19	117	[PRo15]
40.	[Re(bpy)2(CO)2][OTf]	500	[Ru(bpy)3][PF6]	1	TEOA		DMA		405		15	115	[AiR19]
41.	[Fe(qpy)(H2O)2][ClO4]2	5	Ru(bpy)3Cl2	0.02	BIH	0.1	DMF		460 (LED)	1365	0	115	[HEa16]
42.	[Ru(bpy)2HCO][PF6]	0.006	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	21	16	107	[PRo15]
43.	[Ru(bpy)2HCO][PF6]	6.2	[Ir(ppy)2(bpy)][PF6]	0.025	TEOA		NMP		400 - 700	21	16	107	[PRo15]

Category:Photocatalytic CO2 conversion to HCOOH: Difference between revisions

Revision as of 14:10, 18 October 2024

Contents

CO₂ conversion to formic acid[Pro21]

Sacrificial electron donors

Ruthenium Catalysts

Photosensitizers

Experiments

Cobalt Catalysts

Organic and semiconductor photosensitizer

Experiments

Literature

Topics

Category:Photocatalytic CO2 conversion to HCOOH: Difference between revisions

Revision as of 14:10, 18 October 2024

CO2 conversion to formic acid[Pro21]

Sacrificial electron donors

Ruthenium Catalysts

Photosensitizers

Experiments

Cobalt Catalysts

Organic and semiconductor photosensitizer

Experiments

Literature

Current site

Topics

CO₂ conversion to formic acid[Pro21]