Category:Photocatalytic CO2 conversion to HCOOH: Difference between revisions

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</chemform>
</chemform>
== Ruthenium Catalysts ==
== Ruthenium Catalysts ==
<chemform smiles="C1C=CN2[Ru]([*])([*])3(N4C=CC=CC=4C4C=CC=CN=43)N3C=CC=CC=3C=2C=1" isreaction="" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Cl,H,Cl,CO,Cl,MECN,DMF,CO,nPropyl" r2="CO,CO,py,CO,Cl,MECN,DMF,H2O,nPropyl">
<chemform smiles="C1C=CN2[Ru]3(OC(=O)O3)3(N4C=CC=CC=4C4C=CC=CN=43)N3C=CC=CC=3C=2C=1" isreaction="" inchi="1S/2C10H8N2.CH2O3.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2-1(3)4;/h2*1-8H;(H2,2,3,4);/q;;;+2/p-2" inchikey="BEIFWAYVOBNDMH-UHFFFAOYSA-L" height="200px" width="300px" float="none">
  -INDIGO-11022212252D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 27 32 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 3.15699 -3.38618 0.0 0
M  V30 2 C 4.71193 -3.65964 0.0 0
M  V30 3 C 3.96875 -3.07439 0.0 0
M  V30 4 N 4.61923 -4.649 0.0 0
M  V30 5 C 3.02081 -4.29775 0.0 0
M  V30 6 C 3.75249 -4.93542 0.0 0
M  V30 7 C 5.56586 -2.28804 0.0 0
M  V30 8 C 7.19354 -2.44288 0.0 0
M  V30 9 C 6.39609 -1.88025 0.0 0
M  V30 10 C 7.13069 -3.56944 0.0 0
M  V30 11 C 5.45287 -3.3364 0.0 0
M  V30 12 N 6.19768 -4.00478 0.0 0
M  V30 13 C 3.3298 -6.1161 0.0 0
M  V30 14 N 4.78745 -5.86024 0.0 0
M  V30 15 C 4.11177 -5.57836 0.0 0
M  V30 16 C 4.87129 -6.86074 0.0 0
M  V30 17 C 3.37717 -7.01436 0.0 0
M  V30 18 C 4.16086 -7.38506 0.0 0
M  V30 19 C 5.66 -7.17059 0.0 0
M  V30 20 C 7.28798 -6.82859 0.0 0
M  V30 21 N 6.31132 -6.48856 0.0 0
M  V30 22 C 7.47895 -7.92084 0.0 0
M  V30 23 C 5.86553 -8.20872 0.0 0
M  V30 24 C 6.76099 -8.54764 0.0 0
M  V30 25 Ru 5.72176 -5.27974 0.0 0
M  V30 26 R# 6.68759 -4.79856 0.0 0 RGROUPS=(1 1)
M  V30 27 R# 6.72495 -5.6562 0.0 0 RGROUPS=(1 2)
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 2 15 13
M  V30 14 2 16 14
M  V30 15 1 13 17
M  V30 16 1 14 15
M  V30 17 2 17 18
M  V30 18 1 18 16
M  V30 19 2 21 19
M  V30 20 2 22 20
M  V30 21 1 19 23
M  V30 22 1 20 21
M  V30 23 2 23 24
M  V30 24 1 24 22
M  V30 25 1 16 19
M  V30 26 1 2 11
M  V30 27 10 4 25
M  V30 28 10 12 25
M  V30 29 10 25 14
M  V30 30 10 25 21
M  V30 31 10 25 26
M  V30 32 10 25 27
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C([*])1C=CN2~[Ru](~C#O)(~C#O)(~Cl)(~Cl)~N3C=CC([*])=CC=3C=2C=1" isreaction="" inchi="" inchikey="" height="200px" width="300px" float="none" r1="H,tBu">
  -INDIGO-11102215102D
 
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 21 23 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 3.05985 -4.92507 0.0 0
M  V30 2 C 4.79015 -4.92459 0.0 0
M  V30 3 C 3.92664 -4.42497 0.0 0
M  V30 4 N 4.79015 -5.92553 0.0 0
M  V30 5 C 3.05985 -5.93002 0.0 0
M  V30 6 C 3.92882 -6.42503 0.0 0
M  V30 7 C 6.75985 -2.90007 0.0 0
M  V30 8 C 8.49015 -2.89959 0.0 0
M  V30 9 C 7.62664 -2.39997 0.0 0
M  V30 10 C 8.49015 -3.90053 0.0 0
M  V30 11 C 6.75985 -3.90502 0.0 0
M  V30 12 N 7.62882 -4.40003 0.0 0
M  V30 13 R# 2.19382 -4.42507 0.0 0 RGROUPS=(1 1)
M  V30 14 R# 7.62664 -1.39997 0.0 0 RGROUPS=(1 1)
M  V30 15 Ru 6.85 -6.2 0.0 0
M  V30 16 Cl 9.15 -5.55 0.0 0
M  V30 17 Cl 5.675 -7.425 0.0 0
M  V30 18 C 7.10882 -7.16593 0.0 0
M  V30 19 C 7.71603 -6.7 0.0 0
M  V30 20 O 7.62671 -8.02303 0.0 0
M  V30 21 O 8.74102 -6.675 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 1 2 11
M  V30 14 1 1 13
M  V30 15 1 9 14
M  V30 16 8 15 4
M  V30 17 8 15 12
M  V30 18 8 15 17
M  V30 19 8 15 16
M  V30 20 8 15 18
M  V30 21 8 15 19
M  V30 22 3 18 20
M  V30 23 3 19 21
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C1C=CN2[Ru]3(OC(=O)O3)3(N4C=CC=CC=4C4C=CC=CN=43)N3C=CC=CC=3C=2C=1" isreaction="" inchi="1S/2C10H8N2.CH2O3.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2-1(3)4;/h2*1-8H;(H2,2,3,4);/q;;;+2/p-2" inchikey="BEIFWAYVOBNDMH-UHFFFAOYSA-L" height="200px" width="300px" float="none">
   -INDIGO-10312214112D
   -INDIGO-10312214112D


Line 409: Line 282:
M  V30 34 1 27 28
M  V30 34 1 27 28
M  V30 35 2 28 29
M  V30 35 2 28 29
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C1C=CC=N2[Ru]3(P(C4=CC=CC5=C4N3=CC=C5)(C3C=CC=CC=3)C3C=CC=CC=3)3(N4C=CC=CC=4C4C=CC=C(C=12)N=43)N#CC" isreaction="" inchi="1S/C21H16NP.C15H11N3.C2H3N.Ru/c1-3-11-18(12-4-1)23(19-13-5-2-6-14-19)20-15-7-9-17-10-8-16-22-21(17)20;1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;1-2-3;/h1-16H;1-11H;1H3;" inchikey="IPLNYUTYQOJFBH-UHFFFAOYSA-N" height="200px" width="300px" float="none">
  -INDIGO-10312214112D
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 45 54 0 0 0
M  V30 BEGIN ATOM
M  V30 1 C 4.5939 -7.21624 0.0 0
M  V30 2 N 6.22301 -7.42701 0.0 0
M  V30 3 C 5.37505 -6.89206 0.0 0
M  V30 4 C 6.04607 -8.16708 0.0 0
M  V30 5 C 4.55182 -8.01212 0.0 0
M  V30 6 C 5.20614 -8.47479 0.0 0
M  V30 7 C 4.56801 -4.8806 0.0 0
M  V30 8 C 6.21918 -5.11346 0.0 0
M  V30 9 C 5.36782 -4.53644 0.0 0
M  V30 10 N 6.21781 -5.89062 0.0 0
M  V30 11 C 4.5385 -5.69446 0.0 0
M  V30 12 C 5.29697 -6.22729 0.0 0
M  V30 13 C 7.37746 -3.97403 0.0 0
M  V30 14 C 8.82236 -4.15164 0.0 0
M  V30 15 C 8.15871 -3.67951 0.0 0
M  V30 16 C 8.79582 -5.05257 0.0 0
M  V30 17 C 7.20267 -4.78258 0.0 0
M  V30 18 N 8.00331 -5.46537 0.0 0
M  V30 19 C 9.45142 -5.12907 0.0 0
M  V30 20 C 10.9379 -5.0219 0.0 0
M  V30 21 C 10.2124 -4.69048 0.0 0
M  V30 22 C 11.016 -5.84305 0.0 0
M  V30 23 N 9.33561 -5.94737 0.0 0
M  V30 24 C 10.2286 -6.38045 0.0 0
M  V30 25 C 11.7576 -6.16092 0.0 0
M  V30 26 C 11.848 -6.96933 0.0 0
M  V30 27 C 10.2465 -7.17146 0.0 0
M  V30 28 C 11.1394 -7.51942 0.0 0
M  V30 29 C 9.80363 -8.66823 0.0 0
M  V30 30 C 11.5735 -8.95413 0.0 0
M  V30 31 C 10.766 -8.31498 0.0 0
M  V30 32 C 11.4486 -9.95422 0.0 0
M  V30 33 C 9.69538 -9.73392 0.0 0
M  V30 34 C 10.5249 -10.3499 0.0 0
M  V30 35 C 7.26266 -9.12334 0.0 0
M  V30 36 C 8.85427 -9.64062 0.0 0
M  V30 37 C 8.29476 -8.89814 0.0 0
M  V30 38 C 8.51841 -10.5666 0.0 0
M  V30 39 C 6.95825 -10.058 0.0 0
M  V30 40 C 7.59514 -10.7648 0.0 0
M  V30 41 Ru 7.7098 -6.71468 0.0 0
M  V30 42 P 8.86311 -7.83342 0.0 0
M  V30 43 N 7.28155 -7.5694 0.0 0
M  V30 44 C 6.8533 -8.42412 0.0 0
M  V30 45 C 6.42505 -9.27884 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 2 15 13
M  V30 14 2 16 14
M  V30 15 1 13 17
M  V30 16 1 14 15
M  V30 17 2 17 18
M  V30 18 1 18 16
M  V30 19 1 21 19
M  V30 20 1 22 20
M  V30 21 2 19 23
M  V30 22 2 20 21
M  V30 23 1 23 24
M  V30 24 2 24 22
M  V30 25 2 26 25
M  V30 26 1 24 27
M  V30 27 1 25 22
M  V30 28 2 27 28
M  V30 29 1 28 26
M  V30 30 2 31 29
M  V30 31 2 32 30
M  V30 32 1 29 33
M  V30 33 1 30 31
M  V30 34 2 33 34
M  V30 35 1 34 32
M  V30 36 2 37 35
M  V30 37 2 38 36
M  V30 38 1 35 39
M  V30 39 1 36 37
M  V30 40 2 39 40
M  V30 41 1 40 38
M  V30 42 1 8 17
M  V30 43 1 12 3
M  V30 44 1 42 37
M  V30 45 1 42 29
M  V30 46 10 41 43
M  V30 47 3 43 44
M  V30 48 1 44 45
M  V30 49 1 42 27
M  V30 50 10 2 41
M  V30 51 10 41 10
M  V30 52 10 41 18
M  V30 53 10 41 23
M  V30 54 10 41 42
M  V30 END BOND
M  V30 END CTAB
M  END
</chemform><chemform smiles="C1C2N([*])P([Ru](C#O)(C#O)(Cl)3P(N([*])C(N=23)=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1" isreaction="" inchi="" inchikey="" height="200px" width="300px" float="none" r1="Me,H">
  -INDIGO-10312214122D
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 42 48 2 0 0
M  V30 BEGIN ATOM
M  V30 1 C 5.38881 -2.73729 0.0 0
M  V30 2 C 7.07697 -2.67814 0.0 0
M  V30 3 C 6.25115 -2.22114 0.0 0
M  V30 4 C 7.13295 -3.65745 0.0 0
M  V30 5 C 5.37858 -3.76999 0.0 0
M  V30 6 N 6.21178 -4.13634 0.0 0
M  V30 7 C 2.10446 -5.62372 0.0 0
M  V30 8 C 3.85882 -5.88168 0.0 0
M  V30 9 C 3.04496 -5.26083 0.0 0
M  V30 10 C 3.58074 -6.81095 0.0 0
M  V30 11 C 1.95675 -6.54692 0.0 0
M  V30 12 C 2.66589 -7.13732 0.0 0
M  V30 13 C 4.42124 -7.15888 0.0 0
M  V30 14 C 6.0098 -6.92081 0.0 0
M  V30 15 C 5.13478 -6.52711 0.0 0
M  V30 16 C 6.16761 -7.90701 0.0 0
M  V30 17 C 4.53174 -8.13744 0.0 0
M  V30 18 C 5.41924 -8.49086 0.0 0
M  V30 19 C 7.15103 -7.23938 0.0 0
M  V30 20 C 8.74951 -7.02308 0.0 0
M  V30 21 C 7.75913 -6.6567 0.0 0
M  V30 22 C 8.96234 -7.92927 0.0 0
M  V30 23 C 7.35381 -8.19045 0.0 0
M  V30 24 C 8.2736 -8.51264 0.0 0
M  V30 25 C 8.80976 -5.52176 0.0 0
M  V30 26 C 10.453 -4.81535 0.0 0
M  V30 27 C 9.44454 -4.6927 0.0 0
M  V30 28 C 10.8133 -5.68358 0.0 0
M  V30 29 C 9.26389 -6.29905 0.0 0
M  V30 30 C 10.2906 -6.39016 0.0 0
M  V30 31 P 4.9475 -5.58286 0.0 0
M  V30 32 P 7.63614 -5.42738 0.0 0
M  V30 33 N 4.46086 -4.54219 0.0 0
M  V30 34 N 8.04897 -4.27423 0.0 0
M  V30 35 Ru 6.24588 -5.12857 0.0 0
M  V30 36 R# 9.03294 -3.92915 0.0 0 RGROUPS=(1 1)
M  V30 37 R# 3.52683 -4.27654 0.0 0 RGROUPS=(1 1)
M  V30 38 Cl 5.78499 -5.97349 0.0 0
M  V30 39 C 6.55546 -5.85874 0.0 0
M  V30 40 C 6.83931 -4.72558 0.0 0
M  V30 41 O 6.86503 -6.58892 0.0 0
M  V30 42 O 7.43275 -4.32259 0.0 0
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 3 1
M  V30 2 2 4 2
M  V30 3 1 1 5
M  V30 4 1 2 3
M  V30 5 2 5 6
M  V30 6 1 6 4
M  V30 7 2 9 7
M  V30 8 2 10 8
M  V30 9 1 7 11
M  V30 10 1 8 9
M  V30 11 2 11 12
M  V30 12 1 12 10
M  V30 13 2 15 13
M  V30 14 2 16 14
M  V30 15 1 13 17
M  V30 16 1 14 15
M  V30 17 2 17 18
M  V30 18 1 18 16
M  V30 19 2 21 19
M  V30 20 2 22 20
M  V30 21 1 19 23
M  V30 22 1 20 21
M  V30 23 2 23 24
M  V30 24 1 24 22
M  V30 25 2 27 25
M  V30 26 2 28 26
M  V30 27 1 25 29
M  V30 28 1 26 27
M  V30 29 2 29 30
M  V30 30 1 30 28
M  V30 31 1 8 31
M  V30 32 1 31 15
M  V30 33 1 32 21
M  V30 34 1 32 25
M  V30 35 1 33 5
M  V30 36 1 33 31
M  V30 37 1 4 34
M  V30 38 1 34 32
M  V30 39 1 34 36
M  V30 40 1 33 37
M  V30 41 10 31 35
M  V30 42 10 35 6
M  V30 43 10 35 32
M  V30 44 10 35 38
M  V30 45 10 35 39
M  V30 46 10 35 40
M  V30 47 3 39 41
M  V30 48 3 40 42
M  V30 END BOND
M  V30 BEGIN SGROUP
M  V30 1 GEN 1 ATOMS=(2 39 41) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M  V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000)
M  V30 2 GEN 2 ATOMS=(2 40 42) BRKXYZ=(9 0.000000 0.000000 0.000000 0.000000 -
M  V30 0.000000 0.000000 0.000000 0.000000 0.000000) BRKXYZ=(9 0.000000 0.000-
M  V30 000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000)
M  V30 END SGROUP
M  V30 END CTAB
M  END
</chemform><chemform smiles="[Ru]1(N2C=CC=CC=2C2N1=CC=CC=2)([*])12C3N(C4C1=C(N1C=CN([*])C12)C=CC=4)C=CN3[*]" isreaction="" inchi="" inchikey="" height="200px" width="300px" float="none" r1="tBu,Me,tBu,Me" r2="NCMe,NCMe,CO,CO">
  -INDIGO-10312214122D
  0  0  0  0  0  0  0  0  0  0  0 V3000
M  V30 BEGIN CTAB
M  V30 COUNTS 32 39 0 0 0
M  V30 BEGIN ATOM
M  V30 1 Ru 7.53856 -5.2124 0.0 0
M  V30 2 C 6.70334 -2.38111 0.0 0
M  V30 3 C 8.50984 -2.34023 0.0 0
M  V30 4 C 7.56748 -1.94741 0.0 0
M  V30 5 C 8.40481 -3.40362 0.0 0
M  V30 6 C 6.57497 -3.42106 0.0 0
M  V30 7 C 7.44843 -3.89832 0.0 0
M  V30 8 C 5.86989 -6.17513 0.0 0
M  V30 9 C 7.18614 -6.82897 0.0 0
M  V30 10 N 6.78905 -6.08711 0.0 0
M  V30 11 C 6.79804 -7.55667 0.0 0
M  V30 12 C 5.5256 -7.01737 0.0 0
M  V30 13 C 5.99908 -7.64653 0.0 0
M  V30 14 C 7.99631 -6.84069 0.0 0
M  V30 15 C 9.34679 -6.2595 0.0 0
M  V30 16 N 8.35702 -6.14642 0.0 0
M  V30 17 C 9.71179 -7.12608 0.0 0
M  V30 18 C 8.42125 -7.61831 0.0 0
M  V30 19 C 9.24957 -7.72885 0.0 0
M  V30 20 C 6.01083 -4.8703 0.0 0
M  V30 21 C 4.42053 -5.15758 0.0 0
M  V30 22 N 5.24713 -5.56868 0.0 0
M  V30 23 C 4.48941 -4.29356 0.0 0
M  V30 24 N 5.55227 -3.76841 0.0 0
M  V30 25 C 8.87044 -4.889 0.0 0
M  V30 26 C 10.2799 -3.98033 0.0 0
M  V30 27 N 9.20053 -4.05128 0.0 0
M  V30 28 C 10.5164 -4.99042 0.0 0
M  V30 29 N 9.58688 -5.42436 0.0 0
M  V30 30 R# 5.2179 -6.39185 0.0 0 RGROUPS=(1 1)
M  V30 31 R# 9.77473 -6.41048 0.0 0 RGROUPS=(1 1)
M  V30 32 R# 8.13711 -4.4138 0.0 0 RGROUPS=(1 2)
M  V30 END ATOM
M  V30 BEGIN BOND
M  V30 1 2 4 2
M  V30 2 2 5 3
M  V30 3 1 2 6
M  V30 4 1 3 4
M  V30 5 2 6 7
M  V30 6 1 7 5
M  V30 7 2 10 8
M  V30 8 2 11 9
M  V30 9 1 8 12
M  V30 10 1 9 10
M  V30 11 2 12 13
M  V30 12 1 13 11
M  V30 13 2 16 14
M  V30 14 2 17 15
M  V30 15 1 14 18
M  V30 16 1 15 16
M  V30 17 2 18 19
M  V30 18 1 19 17
M  V30 19 1 9 14
M  V30 20 1 20 24
M  V30 21 1 21 22
M  V30 22 1 22 20
M  V30 23 2 23 21
M  V30 24 1 24 23
M  V30 25 1 25 29
M  V30 26 1 26 27
M  V30 27 1 27 25
M  V30 28 2 28 26
M  V30 29 1 29 28
M  V30 30 1 24 6
M  V30 31 1 22 30
M  V30 32 1 27 5
M  V30 33 1 29 31
M  V30 34 10 20 1
M  V30 35 10 1 7
M  V30 36 10 1 25
M  V30 37 10 1 32
M  V30 38 10 1 10
M  V30 39 10 1 16
M  V30 END BOND
M  V30 END BOND
M  V30 END CTAB
M  V30 END CTAB
M  END
M  END
</chemform>
</chemform>
complexes ordered by metal


== Photosensitizers ==
== Photosensitizers ==

Revision as of 14:32, 6 September 2024

CO2 conversion to formic acid[Pro21]

Formic acid (FA) is a simple chemical with many uses. Its applications include use as a preservative, in the leather and dyeing industry and chemical providing a C1 building block. It is also an important H2 carrier, because of its qualities as non-toxic, easily storable liquid. This also makes it directly usable in fuel cells.[Fas16] The global production is currently estimated at 870.000 metric tons in 2021 with a CAGR (Compound Annual Growth Report) of 3.87% in volume terms during the period 2022-2027.[https://www.mordorintelligence.com/industry-reports/formic-acid-market]

Industrial production of formic acid is done mainly by carbonylation of methanol and subsequent hydrolysation of methyl formate to formic acid.[FA00]

A direct approach of synthesis by hydrogenation of CO2 and using renewable energy, such as sunlight in photocatalysis, in a homogeneous environment, is the focus of this page.

Sacrificial electron donors

TEOA TEA BI(OH)H BIH BNAH

Ruthenium Catalysts

Ru(bpy)2CO3

Photosensitizers

Ru(bpy)3Cl2 100832 100489 100533

photosensitizer compounds

Experiments

Entry CAT conc PS conc e-D conc Solvent λex [nm] irr time [h] Sel [%] TON QY [%] reference link to experiment
1 Ru(bpy)3Cl2 - TEOA DMF 400 1 69 4 [Pro85]
2 100549 Ru(bpy)3Cl2 TEOA DMF 400 2 - 326 [Pro90]
3 100550 Ru(bpy)3Cl2 TEOA DMF 400 2 - 255 [Pro90]
4 Ru(bpy)2CO3 Molecule with chemformId 100487 does not exist. TEOA NMP 400 5 78 21 [PRo15]
5 Molecule with key C1C2N([*])P([Ru](C#O)(C#O)(Cl)3P(N([*])C(N=23)=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1r1 does not exist. Ru(bpy)3Cl2 TEOA DMF 405 24 99 380 [VLP19]
6 100552 100533 BI(OH)H/TEOA DMA 500 24 83 3269 [PCR20]

table with several experiments

Cobalt Catalysts

100553 [Show R-Groups] Co(MePP) tBuxant-(Co(qpy))2

Organic and semiconductor photosensitizer

3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine 100494

Experiments

Entry CAT conc PS conc e-D conc Solvent λex [nm] irr time [h] Sel [%] TON reference link to experiment
1 100553 - TEA MeCn 320 >80 245 [CPC98]
2 100553 - TEA MeCn 320 - 120 [CPC98]
3 100553 - TEA MeCn 320 - 120 [CPC98]
4 Co(MePP) - TEA MeCn 320 - 120 [CPC98]
5 Co(MePP) - TEA MeCn 320 - 120 [CPC98]
6 Co(MePP) - TEA MeCn 320 - 120 [CPC98]
7 tBuxant-(Co(qpy))2 Molecule with key DOIVPHUVGVJOMX-UHFFFAOYSA-N does not exist. TEA MeCn 460 92 110 [Sco19]
8 tBuxant-(Co(qpy))2 Molecule with key DOIVPHUVGVJOMX-UHFFFAOYSA-N does not exist. BIH/TEA MeCn 460 97 386 [Sco19]
9 tBuxant-(Co(qpy))2 Molecule with key DOIVPHUVGVJOMX-UHFFFAOYSA-N does not exist. BIH/TEOA MeCn 460 76 821 [Sco19]
10 tBuxant-(Co(qpy))2 3,7-Di((1,1'-biphenyl)-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine BIH/TEOA MeCn 460 58 565 [Sco19]
11 tBuxant-(Co(qpy))2 100494 BIH/TEOA MeCn 460 91 493 [Sco19]

Literature

[Pro21] Photochemical reduction of carbon dioxide to formic acid. Robin Cauwenbergh, Shoubhik Das, Green Chemistry 2021, Vol. 23, Pages 2553-2574. DOI2: 10.1039/d0gc04040a
[Fas16] Formic acid synthesis using CO2 as raw material: Techno-economic and environmental evaluation and market potential. Mar Pérez-Fortes, Jan C. Schöneberger, Aikaterini Boulamanti, Gillian Harrison, Evangelos Tzimas, International Journal of Hydrogen Energy 2016, Vol. 41, Pages 16444-16462. DOI2: 10.1016/j.ijhydene.2016.05.199
[FA00] Formic Acid. Werner Reutemann, Heinz Kieczka, Ullmann's Encyclopedia of Industrial Chemistry 2000. DOI2: 10.1002/14356007.a12_013
[Pro85] Photochemical reduction of carbon dioxide to formate mediated by ruthenium bipyridine complexes as homogeneous catalysts. Jeannot Hawecker, Jean-Marie Lehn, Raymond Ziessel, Journal of the Chemical Society, Chemical Communications 1985, Pages 56. DOI2: 10.1039/c39850000056
[Pro90] Photochemical reduction of carbon dioxide to formate catalyzed by 2,2t́-bipyridine- or 1,10-phenanthroline-ruthenium(II) complexes. Jean-Marie Lehn, Raymond Ziessel, Journal of Organometallic Chemistry 1990, Vol. 382, Pages 157-173. DOI2: 10.1016/0022-328x(90)85224-m
[PCR20] Photocatalytic CO 2 Reduction under Visible‐Light Irradiation by Ruthenium CNC Pincer Complexes. Yasuhiro Arikawa, Itoe Tabata, Yukari Miura, Hiroki Tajiri, Yudai Seto, Shinnosuke Horiuchi, Eri Sakuda, Keisuke Umakoshi, Chemistry – A European Journal 2020, Vol. 26, Pages 5603-5606. DOI2: 10.1002/chem.201905840
Publication: Photocatalytic CO2 Reduction under Visible-Light Irradiation by Ruthenium CNC Pincer Complexes
[CPC98] Cobalt Porphyrin Catalyzed Reduction of CO2. Radiation Chemical, Photochemical, and Electrochemical Studies. D. Behar, T. Dhanasekaran, P. Neta, C. M. Hosten, D. Ejeh, P. Hambright, Etsuko Fujita, The Journal of Physical Chemistry A 1998, Vol. 102, Pages 2870-2877. DOI2: 10.1021/jp9807017
[Sco19] Selectivity control of CO versus HCOO− production in the visible-light-driven catalytic reduction of CO2 with two cooperative metal sites. Zhenguo Guo, Gui Chen, Claudio Cometto, Bing Ma, Hongyan Zhao, Thomas Groizard, Lingjing Chen, Hongbo Fan, Wai-Lun Man, Shek-Man Yiu, Kai-Chung Lau, Tai-Chu Lau, Marc Robert, Nature Catalysis 2019, Vol. 2, Pages 801-808. DOI2: 10.1038/s41929-019-0331-6
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