Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

Latest revision as of 18:12, 19 June 2026

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	feedstock gas	intensity [kW/m²]	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO [TOF/min]	Φ CO [%]	TON H2	TOF H2 [TOF/min]	Φ HCOOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]
[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	987	41.1 h-1		187			84.1%; 0%; 15.9%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	1318	54.9 h-1		243			84.4%; 0%; 15.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	847	35.3 h-1		205			80.5%; 0%; 19.5%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	1265	52.7 h-1		133			90.5%; 0%; 9.5%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	4 h	311	77.7 h-1		51			85.9%; 0%; 14.1%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	48 h	1578	32.9 h-1		296			84.2%; 0%; 15.8%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	96 h	1593	16.6 h-1		300			84.2%; 0%; 15.8%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M			MeCN				CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	2	< 0.1 h-1		22			8.3%; 0%; 91.7%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	10 %	90:10 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	1352	56.3 h-1		285			82.6%; 0%; 17.4%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	30 %	70:30 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	661	27.5 h-1		191			77.6%; 0%; 22.4%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	50 %	50:50 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	621	25.8 h-1		77			89.0%; 0%; 11.0%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	25.0 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	2086	86.9 h-1		123			94.4%; 0%; 5.6%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	12.5 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	4259	177.4 h-1		276			93.9%; 0%; 6.1%; 0%; 0%		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	6.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M			MeCN	H2O	H2O	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	10	168		423.7 h-1	862	7.5 %	n/a	7.5	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.12 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M			MeCN	H2O	H2O	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	23	138		964.1 h-1	2177	7.5 %	n/a	7.5	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzphen)(H2O)2](BF4)2 (Fe1) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	4.8 % (462 nm)	Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	4 h							n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzphen)(H2O)2](BF4)2 (Fe1)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	H2O	7.5 %	MeCN	H2O		92.5:7.5 (v/v)	CO2-saturated CO2	absorbed photon flux 2.16 × 10^-8 einstein s^-1	35 °C	462 nm (blue LED strip)	4 h	9754	2438 h-1	7.6 % (462 nm)				n/a	7.6	<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"%" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"absorbedphotonflux" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li> <!--br--><li>"h-1" is not declared as a valid unit of measurement for this property.</li></ul>
[[[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	3.8 % (462 nm)	Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	4 h							n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>
[[[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4) ]]	3.25 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	0.11 M	7.3 % (462 nm)	Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	4 h							n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>
[[[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2) ]]	50 μM	[[[Ru(bpy)3]2+ ]]	0.3 mM	BIH	27.5 mM		Molecule:100616	MeCN	H2O	7.5 %	92.5:7.5 (v/v)	CO2-saturated CO2		35 °C	462 nm (blue LED strip)	24 h	221						n/a		<ul><li>Property "Catalyst" (as page type) with input value "Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"μM" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>Property "Photosensitizer" (as page type) with input value "Ru(bpy)3]2+" contains invalid characters or is incomplete and therefore can cause unexpected results during a query or annotation process.</li> <!--br--><li>"Molecule:" is not declared as a valid unit of measurement for this property.</li> <!--br--><li>"CO2-saturated CO2" is not in the list (nitrogen, argon, CO2, CO, O2, H2, none) of allowed values for the "Feedstock gas" property.</li> <!--br--><li>"°C" can not be assigned to a declared number type with value 35.</li></ul>

@@ Line 1: / Line 1: @@
 {{Photocatalytic_CO2_conversion_experiments|experiments={{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzphen)(H2O)2](BF4)2 (Fe1)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 8: / Line 8: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=987
-|Turnover_frequency__CO=41.1 h−1
+|Turnover_frequency__CO=41.1 h-1
 |Turnover_number__H2=187
 |Turnover_frequency__H2=
@@ Line 24: / Line 24: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 32: / Line 32: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 39: / Line 39: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=1318
-|Turnover_frequency__CO=54.9 h−1
+|Turnover_frequency__CO=54.9 h-1
 |Turnover_number__H2=243
 |Turnover_frequency__H2=
@@ Line 55: / Line 55: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 63: / Line 63: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzPhphen)(H2O)2](ClO4)2 (Fe3)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 70: / Line 70: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=847
-|Turnover_frequency__CO=35.3 h−1
+|Turnover_frequency__CO=35.3 h-1
 |Turnover_number__H2=205
 |Turnover_frequency__H2=
@@ Line 86: / Line 86: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 94: / Line 94: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzCF3phen)(H2O)2](ClO4)2 (Fe4)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 101: / Line 101: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=1265
-|Turnover_frequency__CO=52.7 h−1
+|Turnover_frequency__CO=52.7 h-1
 |Turnover_number__H2=133
 |Turnover_frequency__H2=
@@ Line 117: / Line 117: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 125: / Line 125: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 132: / Line 132: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=4 h
 |Turnover_number__CO=311
-|Turnover_frequency__CO=77.7 h−1
+|Turnover_frequency__CO=77.7 h-1
 |Turnover_number__H2=51
 |Turnover_frequency__H2=
@@ Line 148: / Line 148: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 156: / Line 156: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 163: / Line 163: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=48 h
 |Turnover_number__CO=1578
-|Turnover_frequency__CO=32.9 h−1
+|Turnover_frequency__CO=32.9 h-1
 |Turnover_number__H2=296
 |Turnover_frequency__H2=
@@ Line 179: / Line 179: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 187: / Line 187: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 194: / Line 194: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=96 h
 |Turnover_number__CO=1593
-|Turnover_frequency__CO=16.6 h−1
+|Turnover_frequency__CO=16.6 h-1
 |Turnover_number__H2=300
 |Turnover_frequency__H2=
@@ Line 210: / Line 210: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 218: / Line 218: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 226: / Line 226: @@
 |solvent B=
 |solvent-ratio=
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=2
-|Turnover_frequency__CO=< 0.1 h−1
+|Turnover_frequency__CO=< 0.1 h-1
 |Turnover_number__H2=22
 |Turnover_frequency__H2=
@@ Line 249: / Line 249: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 256: / Line 256: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=10% H2O (v/v)
+|solvent-ratio=90:10 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=1352
-|Turnover_frequency__CO=56.3 h−1
+|Turnover_frequency__CO=56.3 h-1
 |Turnover_number__H2=285
 |Turnover_frequency__H2=
@@ Line 272: / Line 272: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=10 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 280: / Line 280: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 287: / Line 287: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=30% H2O (v/v)
+|solvent-ratio=70:30 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=661
-|Turnover_frequency__CO=27.5 h−1
+|Turnover_frequency__CO=27.5 h-1
 |Turnover_number__H2=191
 |Turnover_frequency__H2=
@@ Line 303: / Line 303: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=30 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 311: / Line 311: @@
 {{Photocatalytic_CO2_conversion
 |catalyst=[Fe(bpzMe2phen)(H2O)2](BF4)2 (Fe2)
-|cat conc=50.0 μM
+|cat conc=50 μM
 |PS=[Ru(bpy)3]2+
 |PS conc=0.3 mM
@@ Line 318: / Line 318: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=50% H2O (v/v)
+|solvent-ratio=50:50 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=621
-|Turnover_frequency__CO=25.8 h−1
+|Turnover_frequency__CO=25.8 h-1
 |Turnover_number__H2=77
 |Turnover_frequency__H2=
@@ Line 334: / Line 334: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=50 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 349: / Line 349: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=2086
-|Turnover_frequency__CO=86.9 h−1
+|Turnover_frequency__CO=86.9 h-1
 |Turnover_number__H2=123
 |Turnover_frequency__H2=
@@ Line 365: / Line 365: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 380: / Line 380: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
 |irr time=24 h
 |Turnover_number__CO=4259
-|Turnover_frequency__CO=177.4 h−1
+|Turnover_frequency__CO=177.4 h-1
 |Turnover_number__H2=276
 |Turnover_frequency__H2=
@@ Line 396: / Line 396: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 411: / Line 411: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
@@ Line 418: / Line 418: @@
 |Turnover_number__CO=10
 |Turnover_frequency__CO=168
-|Turnover_number__H2=423.7 h−1
+|Turnover_number__H2=423.7 h-1
 |Turnover_frequency__H2=862
 |additives=
@@ Line 428: / Line 428: @@
 |H-D=
 |H-D conc=
-|solvent C=
+|solvent C=Molecule:100616
-|Quantum_yield__HCOOH=
+|Quantum_yield__HCOOH=7.5 %
 |pH=
 |Turnover_frequency__HCOOH=
@@ Line 442: / Line 442: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
@@ Line 449: / Line 449: @@
 |Turnover_number__CO=23
 |Turnover_frequency__CO=138
-|Turnover_number__H2=964.1 h−1
+|Turnover_number__H2=964.1 h-1
 |Turnover_frequency__H2=2177
 |additives=
@@ Line 459: / Line 459: @@
 |H-D=
 |H-D conc=
-|solvent C=
+|solvent C=Molecule:100616
-|Quantum_yield__HCOOH=
+|Quantum_yield__HCOOH=7.5 %
 |pH=
 |Turnover_frequency__HCOOH=
@@ Line 473: / Line 473: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
-|λexc=462 nm
+|λexc=462 nm (blue LED strip)
 |irr time=4 h
 |Turnover_number__CO=
@@ Line 484: / Line 484: @@
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
+|intensity=
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=4.8%
+|Quantum_yield__CO=
-|H-D=
+|H-D=4.8 % (462 nm)
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 504: / Line 504: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
-|λexc=462 nm
+|λexc=462 nm (blue LED strip)
 |irr time=4 h
 |Turnover_number__CO=9754
-|Turnover_frequency__CO=2438 h−1
+|Turnover_frequency__CO=2438 h-1
 |Turnover_number__H2=
 |Turnover_frequency__H2=
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
+|intensity=absorbed photon flux 2.16 × 10^-8 einstein s^-1
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=7.6%
+|Quantum_yield__CO=7.6 % (462 nm)
-|H-D=
+|H-D=Molecule:100616
-|H-D conc=
+|H-D conc=7.5 %
 |solvent C=
 |Quantum_yield__HCOOH=
@@ Line 535: / Line 535: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
-|λexc=462 nm
+|λexc=462 nm (blue LED strip)
 |irr time=4 h
 |Turnover_number__CO=
@@ Line 546: / Line 546: @@
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
+|intensity=
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=3.8%
+|Quantum_yield__CO=
-|H-D=
+|H-D=3.8 % (462 nm)
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 566: / Line 566: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
-|λexc=462 nm
+|λexc=462 nm (blue LED strip)
 |irr time=4 h
 |Turnover_number__CO=
@@ Line 577: / Line 577: @@
 |additives=
 |Turnover_number__HCOOH=
-|intensity=absorbed photon flux 2.16 × 10−8 einstein s−1
+|intensity=
 |Turnover_number__CH4=
 |additives conc=
-|Quantum_yield__CO=7.2%
+|Quantum_yield__CO=
-|H-D=
+|H-D=7.3 % (462 nm)
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=
@@ Line 597: / Line 597: @@
 |solvent A=Molecule:100530
 |solvent B=Molecule:100616
-|solvent-ratio=7.5% H2O (v/v)
+|solvent-ratio=92.5:7.5 (v/v)
-|feedstock gas=CO2-saturated
+|feedstock gas=CO2-saturated CO2
 |Temperature=35 °C
 |λexc=462 nm (blue LED strip)
@@ Line 613: / Line 613: @@
 |Quantum_yield__CO=
 |H-D=
-|H-D conc=
+|H-D conc=Molecule:100616
-|solvent C=
+|solvent C=7.5 %
 |Quantum_yield__HCOOH=
 |pH=

Iron(II) bis(pyrazolyl)phenanthroline complexes as robust and efficient homogeneous catalysts for CO2-to-CO conversion under visible light/inv0: Difference between revisions

Latest revision as of 18:12, 19 June 2026

Current site

Topics