Iron-Catalyzed Photochemical CO2 Reduction under diverse conditions error

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< Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction
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investigation
Molecular process, Photocatalytic CO2 conversion experiments
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cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100968

2

Ru(bpy)3

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90-120 15520 86 99.4%; 0%; 0.6%; 0%; 0%


in 5 mL solvent true

Molecule:100968

0.2

Ru(bpy)3

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90-120 30349 1013 96.8%; 0%; 3.2%; 0%; 0%


in 5 mL solvent true


Ru(bpy)3

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90-120 43 52 45.3%; 0%; 54.7%; 0%; 0%


in 5 mL solvent true

Molecule:100968

2


BIH

0.1

PhOH

1

MeCN



CO2 90-120 112 0 n/a


in 5 mL solvent true

Molecule:100968

2

Ru(bpy)3

0.2


PhOH

1

MeCN



CO2 90-120 150 0 n/a


in 5 mL solvent true

Molecule:100968

2

Ru(bpy)3

0.2

BIH

0.1


1

MeCN



CO2 90-120 6 0 n/a


in 5 mL solvent true

Molecule:100968

2

Ru(bpy)3

0.2

BIH

0.1

PhOH

1

MeCN



Ar 90-120 0 222 n/a


in 5 mL solvent true

Molecule:100968

2

Molecule:100971

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90-120 12749 163 98.7%; 0%; 1.3%; 0%; 0%


in 5 mL solvent true

Molecule:100968

0.2

Molecule:100971

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90-120 28712 6527 81.5%; 0%; 18.5%; 0%; 0%


in 5 mL solvent true

Molecule:100968

2

Ir(ppy)3

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90-120 18502 141 99.2%; 0%; 0.8%; 0%; 0%


in 5 mL solvent true

Molecule:100968

2

Molecule:100970

0.2

BIH

0.1

PhOH

1

MeCN



CO2 90-120 6710 0 n/a


in 5 mL solvent true