Exchange Coupling Determines Metal-Dependent Efficiency for Iron- and Cobalt-Catalyzed Photochemical CO2 Reduction/Iron-Catalyzed Photochemical CO2 Reduction under diverse conditions error

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90	15520						86									99.4%; 0%; 0.6%; 0%; 0%		in 5 mL solvent	true
Molecule:100968	0.2	Ru(bpy)3	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90	30349						1013									96.8%; 0%; 3.2%; 0%; 0%		in 5 mL solvent	true
		Ru(bpy)3	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90	43						52									45.3%; 0%; 54.7%; 0%; 0%		in 5 mL solvent	true
Molecule:100968	2			BIH	0.1	PhOH	1	MeCN						CO2						90	112						0									n/a		in 5 mL solvent	true
Molecule:100968	2	Ru(bpy)3	0.2			PhOH	1	MeCN						CO2						90	150						0									n/a		in 5 mL solvent	true
Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1		1	MeCN						CO2						90	6						0									n/a		in 5 mL solvent	true
Molecule:100968	2	Ru(bpy)3	0.2	BIH	0.1	PhOH	1	MeCN				Ar								90	0						222									n/a		in 5 mL solvent	true
Molecule:100968	2	Molecule:100971	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90	12749						163									98.7%; 0%; 1.3%; 0%; 0%		in 5 mL solvent	true
Molecule:100968	0.2	Molecule:100971	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90	28712						6527									81.5%; 0%; 18.5%; 0%; 0%		in 5 mL solvent	true
Molecule:100968	2	Ir(ppy)3	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90	18502						141									99.2%; 0%; 0.8%; 0%; 0%		in 5 mL solvent	true
Molecule:100968	2	Molecule:100970	0.2	BIH	0.1	PhOH	1	MeCN						CO2						90	6710						0									n/a		in 5 mL solvent	true