Table 1

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< Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
Revision as of 22:50, 27 December 2023 by 127.0.0.1 (talk) (auto-generated)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

[Ni(bimiqpr)][PF6]2

0.000002

Molecule:100806

0.2

TEA

0.07


MeCN



solar spectrum 7 98000 3.9 0.01 n/a

0.01

Yes

[Ni(bimiqpr)][PF6]2

0.00002

Molecule:100806

0.2

TEA

0.07


MeCN



solar spectrum 7 9000 0.36 n/a


Yes

[Ni(bimiqpr)][PF6]2

0.0002

Molecule:100806

0.2

TEA

0.07


MeCN



solar spectrum 7 1500 0.058 n/a


Yes

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