Photocatalytic CO2 conversion to CH4

TON CH4 >100

TON CH4 < 100

Literature

[DSP19] Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO₂ or CO to CH₄. Hunter Shirley, Xiaojun Su, Harshin Sanjanwala, Kallol Talukdar, Jonah W. Jurss, Jared H. Delcamp, Journal of the American Chemical Society 2019, Vol. 141, Pages 6617-6622. DOI2: 10.1021/jacs.9b00937
Publication: Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4

[Vld17] Visible-light-driven methane formation from CO2 with a molecular iron catalyst. Heng Rao, Luciana C. Schmidt, Julien Bonin, Marc Robert, Nature 2017, Vol. 548, Pages 74-77. DOI2: 10.1038/nature23016
Publication: Visible-light-driven methane formation from CO2 with a molecular iron catalyst

[VLD18] Visible-Light-Driven Conversion of CO₂ to CH₄ with an Organic Sensitizer and an Iron Porphyrin Catalyst. Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert, Journal of the American Chemical Society 2018, Vol. 140, Pages 17830-17834. DOI2: 10.1021/jacs.8b09740
Publication: Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	lit
1.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		570000		[DSP19]
2.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		130000	29000	4900000	[DSP19]
3.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000	[DSP19]
4.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000		[DSP19]
5.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		10000	58000	[DSP19]
6.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000	[DSP19]
7.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000	[DSP19]
8.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		5000	1000	15000	[DSP19]
9.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		195	45	[TVL18]
10.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		159	34	[Vld17]
11.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			140	28	[Vld17]
12.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		100	19	[TVL18]

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	lit
1.	Fe(DHPP)Cl	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		139	26	15	[Vld17]
2.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	71	14	10	[VLD18]
3.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			89	18	[TVL18]
4.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24	[TVL18]
5.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		134	23	67	[TVL18]
6.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		100	19	[TVL18]
7.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		24	3	5	[TVL18]
8.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		178	32	103	[TVL18]
9.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		151	24	77	[TVL18]
10.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		19	3	4	[TVL18]
11.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	240	66	73	[Vld17]
12.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		20	3	4	[TVL18]
13.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		367	79	26	[Vld17]
14.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	140	29	23	[VLD18]
15.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF		50	8	8	[VLD18]
16.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			89	18	[Vld17]
17.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24	[Vld17]