Photocatalytic CO2 conversion to CH4

TON CH4 >100

TON CH4 < 100{{#experimentlink:%5B%5BTurnover%20number%20CH4%3A%3A%3C100%5D%5D|form=Photocatalytic_CO2_conversion_experiments|restrictToPages=|sort=Catalyst|order=}}

Literature

[DSP19] Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO₂ or CO to CH₄. Hunter Shirley, Xiaojun Su, Harshin Sanjanwala, Kallol Talukdar, Jonah W. Jurss, Jared H. Delcamp, Journal of the American Chemical Society 2019, Vol. 141, Pages 6617-6622. DOI2: 10.1021/jacs.9b00937
Publication: Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4

[TVL18] Toward Visible-Light Photochemical CO₂-to-CH₄ Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis. Heng Rao, Julien Bonin, Marc Robert, The Journal of Physical Chemistry C 2018, Vol. 122, Pages 13834-13839. DOI2: 10.1021/acs.jpcc.8b00950
Publication: Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis

[Vld17] Visible-light-driven methane formation from CO2 with a molecular iron catalyst. Heng Rao, Luciana C. Schmidt, Julien Bonin, Marc Robert, Nature 2017, Vol. 548, Pages 74-77. DOI2: 10.1038/nature23016
Publication: Visible-light-driven methane formation from CO2 with a molecular iron catalyst

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	lit
1.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		570000		[DSP19]
2.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		130000	29000	4900000	[DSP19]
3.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000	[DSP19]
4.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000		[DSP19]
5.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		10000	58000	[DSP19]
6.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000	[DSP19]
7.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000	[DSP19]
8.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		5000	1000	15000	[DSP19]
9.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		195	45	[TVL18]
10.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		159	34	[Vld17]
11.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			140	28	[Vld17]
12.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		100	19	[TVL18]

Photocatalytic CO2 conversion to CH4

Literature

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