Photocatalytic CO2 conversion to CH4

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TON CH4 >1

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e-D conc 0.01

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Literature

[DSP19] Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO₂ or CO to CH₄. Hunter Shirley, Xiaojun Su, Harshin Sanjanwala, Kallol Talukdar, Jonah W. Jurss, Jared H. Delcamp, Journal of the American Chemical Society 2019, Vol. 141, Pages 6617-6622. DOI2: 10.1021/jacs.9b00937
Publication: Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH4

[TVL18] Toward Visible-Light Photochemical CO₂-to-CH₄ Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis. Heng Rao, Julien Bonin, Marc Robert, The Journal of Physical Chemistry C 2018, Vol. 122, Pages 13834-13839. DOI2: 10.1021/acs.jpcc.8b00950
Publication: Toward Visible-Light Photochemical CO2‑to-CH4 Conversion in Aqueous Solutions Using Sensitized Molecular Catalysis

[VLD18] Visible-Light-Driven Conversion of CO₂ to CH₄ with an Organic Sensitizer and an Iron Porphyrin Catalyst. Heng Rao, Chern-Hooi Lim, Julien Bonin, Garret M. Miyake, Marc Robert, Journal of the American Chemical Society 2018, Vol. 140, Pages 17830-17834. DOI2: 10.1021/jacs.8b09740
Publication: Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

[Vld17] Visible-light-driven methane formation from CO2 with a molecular iron catalyst. Heng Rao, Luciana C. Schmidt, Julien Bonin, Marc Robert, Nature 2017, Vol. 548, Pages 74-77. DOI2: 10.1038/nature23016
Publication: Visible-light-driven methane formation from CO2 with a molecular iron catalyst

[EtF21] Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re ₂ Cl ₂ Complex Assisted by Various Photosensitizers. Robin Giereth, Martin Obermeier, Lukas Forschner, Michael Karnahl, Matthias Schwalbe, Stefanie Tschierlei, ChemPhotoChem 2021, Vol. 5, Pages 644-653. DOI2: 10.1002/cptc.202100034
Publication: Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers

[HEa18] Highly Efficient and Robust Photocatalytic Systems for CO₂ Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts. Hiroyuki Takeda, Hiroko Kamiyama, Kouhei Okamoto, Mina Irimajiri, Toshihide Mizutani, Kazuhide Koike, Akiko Sekine, Osamu Ishitani, Journal of the American Chemical Society 2018, Vol. 140, Pages 17241-17254. DOI2: 10.1021/jacs.8b10619
Publication: Highly Efficient and Robust Photocatalytic Systems for CO2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts

[PpC21] Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore. Huiqing Yuan, Banggui Cheng, Jingxiang Lei, Long Jiang, Zhiji Han, Nature Communications 2021, Vol. 12. DOI2: 10.1038/s41467-021-21923-9
Publication: Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	lit
1.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		10000	58000	[DSP19]
2.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		570000		[DSP19]
3.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000	[DSP19]
4.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000	[DSP19]
5.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000	[DSP19]
6.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000		[DSP19]
7.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		5000	1000	15000	[DSP19]
8.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	TEA		MeCN		130000	29000	4900000	[DSP19]
9.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		19	3	4	[TVL18]
10.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		151	24	77	[TVL18]
11.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24	[TVL18]
12.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		195	45	[TVL18]
13.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		100	19	[TVL18]
14.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			89	18	[TVL18]
15.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	DIPEA	0.05	MeCN		20	3	4	[TVL18]
16.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		24	3	5	[TVL18]
17.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEOA	0.05	MeCN		134	23	67	[TVL18]
18.	Fe(pTMAPP)Cl5	0.002	[Ir(ppy)2(bpy)][PF6]	0.2	TEA	0.05	MeCN		178	32	103	[TVL18]
19.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF		50	8	8	[VLD18]
20.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	140	29	23	[VLD18]
21.	Fe(pTMAPP)Cl5	0.01	Molecule:100493	1	TEA	0.1	DMF	TFE	71	14	10	[VLD18]
22.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE	240	66	73	[Vld17]
23.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		198	31	24	[Vld17]
24.	Fe(DHPP)Cl	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		139	26	15	[Vld17]
25.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN		367	79	26	[Vld17]
26.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN	TFE		159	34	[Vld17]
27.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			140	28	[Vld17]
28.	Fe(pTMAPP)Cl5	0.002	Ir(ppy)3	0.2	TEA	0.05	MeCN			89	18	[Vld17]

	cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	solvent A	additives	TON CO	TON CH4	TON H2	TON HCOOH	lit
1.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		10000	58000		[DSP19]
2.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA 5% (v/v), H2O 2% (v/v)		570000			[DSP19]
3.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	8000	5000	34000		[DSP19]
4.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	108000	4000	278000		[DSP19]
5.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	175000	19000	29000		[DSP19]
6.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	51000	12000			[DSP19]
7.	[Ni(bpy)-(MeNHC)2][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA, H2O	31000		320000		[DSP19]
8.	[Ni(bpy-bNHCMe)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	76000		17000		[DSP19]
9.	[Ni(bpy-bNHCEt)][PF6]2	2.0E-6	Ir(ppy)3	0.1	BIH	0.01	MeCN	TEA	310000		33000		[DSP19]
10.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.01	DMF	TEA	131				[EtF21]
11.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.005	BIH	0.01	DMF	TEA	124				[EtF21]
12.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.0125	BIH	0.01	DMF	TEA	144				[EtF21]
13.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.05	BIH	0.01	DMF	TEA	195				[EtF21]
14.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	[Cu(bcp)(xant)][PF6]	0.05	BIH	0.01	DMF	TEA	169				[EtF21]
15.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05			BIH	0.01	DMF	TEA	63				[EtF21]
16.	(tBuxant)-(Re(bpy)(CO)3Cl)2	0.05	Ir(fppy)3	0.025	BIH	0.01	DMF	TEA	149				[EtF21]
17.	Mn(oMesbpy)(CO)2Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		208		0.5	5	[HEa18]
18.	Mn(bpy)(CO)3Br	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		50		4	157	[HEa18]
19.	Molecule:100845	0.05	[Cu(phen)-(dPPh-Bu)2]2[PF6]2	0.25	BIH	0.01	MeCN		164		1	65	[HEa18]
20.	Fe(DHPP)Cl	0.0002	purpurin	0.1	BIH	0.01	DMF		88		0		[PpC21]
21.	Fe(DHPP)Cl	0.0002	[Cu(PP)2][TBA]2	0.1	BIH	0.01	DMF		4779		270		[PpC21]

Photocatalytic CO2 conversion to CH4

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