Table 1
From ChemWiki
< Visible-Light Photocatalytic Reduction of CO2 to Formic Acid with a Ru Catalyst Supported by N,N’- Bis(diphenylphosphino)-2,6-diaminopyridine Ligands
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.025 | 0.025 |
|
|
|
405 | 24 | 380 | n/a |
|
Yes | |||||||||||||||||||||||||||||
| 0.05 | 0.05 |
|
|
|
405 | 14 | 210 | n/a |
|
Yes | |||||||||||||||||||||||||||||
| 0.1 | 0.1 |
|
|
|
405 | 24 | 57.5 | 363 | 0%; 0%; 13.7%; 86.3%; 0% |
|
Yes | ||||||||||||||||||||||||||||
| 0.5 | 1 |
|
|
|
405 | 24 | 14 | 70.5 | 0%; 0%; 16.6%; 83.4%; 0% |
|
Yes | ||||||||||||||||||||||||||||
| 1 | 1 |
|
|
|
405 | 24 | 13.3 | 90.5 | 0%; 0%; 12.8%; 87.2%; 0% |
|
Yes | ||||||||||||||||||||||||||||
| 0.5 | 1 |
|
|
|
405 | 24 | 14 | 70.5 | 0%; 0%; 16.6%; 83.4%; 0% |
|
Yes | ||||||||||||||||||||||||||||
| 1 | 1 |
|
|
|
405 | 24 | 12 | 44.5 | 0%; 0%; 21.2%; 78.8%; 0% |
|
Yes | ||||||||||||||||||||||||||||
| 2 | 1 |
|
|
|
405 | 9.3 | 41.5 | 0%; 0%; 18.3%; 81.7%; 0% |
|
Yes |
