Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
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publication
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| DOI | 10.1021/ja4074003 |
| Authors | V. Sara Thoi, Nikolay Kornienko, Charles G. Margarit, Peidong Yang, Christopher J. Chang, |
| Submitted | 13.09.2013 |
| Published online | 13.09.2013 |
| Licenses | - |
| Subjects | Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis |
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| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | λexc [nm] | . | TON CO | . | . | . | . | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1. | 0.002 | 0.2 | 0.07 | solar spectrum | 98000 | |||||||||
| 2. | 0.02 | 0.2 | 0.07 | solar spectrum | 9000 | |||||||||
| 3. | 0.2 | 0.2 | 0.07 | solar spectrum | 1500 |
