Table 1

From ChemWiki
< Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
Revision as of 16:15, 20 January 2023 by ChN (talk | contribs) (Created page with "{{Photocatalytic CO2 conversion experiments |experiments={{Photocatalytic CO2 conversion |catalyst=Molecule:100637 |cat conc=0.000002 |PS=Molecule:100626 |PS conc=0.2 |e-D=Mol...")
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)

investigation
Molecular process, Photocatalytic CO2 conversion experiments
cat cat conc [µM] PS PS conc [mM] e-D e-D conc [M] H-D H-D conc [M] solvent A solvent B solvent C solv A/B/C additives additives conc [M] feedstock gas feedstock volume intensity pH T [°C] λexc [nm] t [h] TON CO TOF CO Φ CO [%] TON CH4 TOF CH4 Φ CH4 [%] TON H2 TOF H2 Φ H2 [%] TON HCOOH TOF HCOOH Φ HCOOH [%] TON MeOH TOF MeOH Φ MeOH [%] selectivity [%] [CO;CH4;H2;HCOOH;MeOH] Φ all [%] Details include

Molecule:100637

0.000002

Molecule:100626

0.2

TEA

0.07


MeCN



solar spectrum 7 98000 3.9 0.01 n/a

0.01

Yes

Molecule:100637

0.00002

Molecule:100626

0.2

TEA

0.07


MeCN



solar spectrum 7 9000 0.36 n/a


Yes

Molecule:100637

0.0002

Molecule:100626

0.2

TEA

0.07


MeCN



solar spectrum 7 1500 0.058 n/a


Yes