Control experiments
From ChemWiki
< Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid
investigation
Molecular process, Photocatalytic CO2 conversion experiments
investigation
| cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 0.02 |
|
|
|
|
9:1 | Hg | 0.17 | CO2 | 25 | >400 | 24 | 69 | 0.9 | 291 | 19.1%; 0%; 0.2%; 80.6%; 0% |
|
No | ||||||||||||||||||||||
| 0.02 |
|
|
|
|
9:1 | CO2 | 25 | >400 | 24 | 62 | 0.8 | 323 | 16.1%; 0%; 0.2%; 83.7%; 0% |
|
No | ||||||||||||||||||||||||
| 0.02 |
|
|
|
|
|
CO2 | 25 | >400 | 24 | 3.9 | 0.9 | 188 | 2.0%; 0%; 0.5%; 97.5%; 0% |
|
No | ||||||||||||||||||||||||
| 0.02 |
|
|
|
9:1:2 | CO2 | 25 | >400 | 24 | 57 | 5 | 115 | 32.2%; 0%; 2.8%; 65.0%; 0% |
|
No |
