Table 1
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< Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
investigation
Molecular process, Photocatalytic CO2 conversion experimentscat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | H-D | H-D conc [M] | solvent A | solvent B | solvent C | solv A/B/C | additives | additives conc [M] | feedstock gas | feedstock volume | intensity | pH | T [°C] | λexc [nm] | t [h] | TON CO | TOF CO | Φ CO [%] | TON CH4 | TOF CH4 | Φ CH4 [%] | TON H2 | TOF H2 | Φ H2 [%] | TON HCOOH | TOF HCOOH | Φ HCOOH [%] | TON MeOH | TOF MeOH | Φ MeOH [%] | selectivity [%] [CO;CH4;H2;HCOOH;MeOH] | Φ all [%] | Details | include |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
0.000002 | 0.2 | 0.07 |
|
|
|
solar spectrum | 7 | 98000 | 3.9 | 0.01 | n/a |
0.01 |
Yes | ||||||||||||||||||||||||||
0.00002 | 0.2 | 0.07 |
|
|
|
solar spectrum | 7 | 9000 | 0.36 | n/a |
|
Yes | |||||||||||||||||||||||||||
0.0002 | 0.2 | 0.07 |
|
|
|
solar spectrum | 7 | 1500 | 0.058 | n/a |
|
Yes |