New Photosensitizers Based on Heteroleptic Cu(I) Complexes and CO2 Photocatalytic Reduction with (Ni(II)(cyclam))Cl2/Photocatalytic CO2 reduction and control experiments

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.02			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	4.3															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.02			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	4.9															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.02			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	8.1															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100909	1	BIH	0.02			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	4.6															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	2.6															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100907	1	BIH	0.01			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	3.5															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	5.0															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100909	1	BIH	0.01			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4	1.8															n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100906	1	BIH	0.01			MeCN	TEOA		4:1			CO2				23	420 nm (4 x 8 W)	4	2.8															n/a			No
		Molecule:100908	1	BIH	0.01			MeCN	TEOA		5:1			CO2				23	420 nm (4 x 8 W)	4																n/a			No
Ni(cyclam)Cl2	0.1	Molecule:100908	1	BIH	0.01			MeCN			5:1			CO2				23	420 nm (4 x 8 W)	4																n/a			No