Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid/Control experiments

cat	cat conc [µM]	PS	PS conc [mM]	e-D	e-D conc [M]	H-D	H-D conc [M]	solvent A	solvent B	solvent C	solv A/B/C	additives	additives conc [M]	feedstock gas	feedstock volume	intensity	pH	T [°C]	λexc [nm]	t [h]	TON CO	TOF CO	Φ CO [%]	TON CH4	TOF CH4	Φ CH4 [%]	TON H2	TOF H2	Φ H2 [%]	TON HCOOH	TOF HCOOH	Φ HCOOH [%]	TON MeOH	TOF MeOH	Φ MeOH [%]	selectivity [%] [CO;CH4;H2;HCOOH;MeOH]	Φ all [%]	Details	include
[Ir(mesbpy-(PCy2)2)][BPh4]	0.02							DMA	H2O		9:1	Hg	0.17	CO2				25	>400	24	69						0.9			291						19.1%; 0%; 0.2%; 80.6%; 0%			No
[Ir(mesbpy-(PCy2)2)][BPh4]	0.02							DMA	H2O		9:1			CO2				25	>400	24	62						0.8			323						16.1%; 0%; 0.2%; 83.7%; 0%			No
[Ir(mesbpy-(PCy2)2)][BPh4]	0.02							DMA						CO2				25	>400	24	3.9						0.9			188						2.0%; 0%; 0.5%; 97.5%; 0%			No
[Ir(mesbpy-(PCy2)2)][BPh4]	0.02							DMA	H2O	TEOA	9:1:2			CO2				25	>400	24	57						5			115						32.2%; 0%; 2.8%; 65.0%; 0%			No