Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex: Difference between revisions

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DOI 10.1021/ja4074003
Authors V. Sara Thoi, Nikolay Kornienko, Charles G. Margarit, Peidong Yang, Christopher J. Chang,
Submitted 13.09.2013
Published online 13.09.2013
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Subjects Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis
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=== Abstract ===
 
==== Summary ====
 
==== Advances and special progress ====
 
==== Additional remarks ====
 
=== Content of the published article in detail ===
 
==== Catalyst====
==== Catalyst====
{{#moleculelink:|link=CFQFJQWFSHKEAB-UHFFFAOYSA-N|image=true}}
{{#moleculelink:|link=CFQFJQWFSHKEAB-UHFFFAOYSA-N|image=true}}

Revision as of 08:30, 12 January 2024


Abstract

Summary

Advances and special progress

Additional remarks

Content of the published article in detail

Catalyst

[Ni(bimiqpr)][PF6]2

Photosensitizer

Ir(ppy)3

Investigation

catcat conc [µM]PSPS conc [mM]e-De-D conc [M]solvent Aλexc [nm].TON CO....
1.

[Ni(bimiqpr)][PF6]2

0.000002

Ir(ppy)3

0.2

TEA

0.07

MeCN

solar spectrum98000
2.

[Ni(bimiqpr)][PF6]2

0.00002

Ir(ppy)3

0.2

TEA

0.07

MeCN

solar spectrum9000
3.

[Ni(bimiqpr)][PF6]2

0.0002

Ir(ppy)3

0.2

TEA

0.07

MeCN

solar spectrum1500
Experiment-Name: Table 1

Sacrificial electron donor

TEA Please remove this!

Investigations

  • Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)