Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex: Difference between revisions
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{{#doiinfobox: 10.1021/ja4074003}} | {{#doiinfobox: 10.1021/ja4074003}} | ||
=== Abstract === | |||
==== Summary ==== | |||
==== Advances and special progress ==== | |||
==== Additional remarks ==== | |||
=== Content of the published article in detail === | |||
==== Catalyst==== | ==== Catalyst==== | ||
{{#moleculelink:|link=CFQFJQWFSHKEAB-UHFFFAOYSA-N|image=true}} | {{#moleculelink:|link=CFQFJQWFSHKEAB-UHFFFAOYSA-N|image=true}} |
Revision as of 08:30, 12 January 2024
Abstract
Summary
Advances and special progress
Additional remarks
Content of the published article in detail
Catalyst
Photosensitizer
Investigation
cat | cat conc [µM] | PS | PS conc [mM] | e-D | e-D conc [M] | solvent A | λexc [nm] | . | TON CO | . | . | . | . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1. | 0.000002 | 0.2 | 0.07 | solar spectrum | 98000 | |||||||||
2. | 0.00002 | 0.2 | 0.07 | solar spectrum | 9000 | |||||||||
3. | 0.0002 | 0.2 | 0.07 | solar spectrum | 1500 |
Experiment-Name: Table 1
Sacrificial electron donor
TEA Please remove this!
Investigations
- Table 1 (Molecular process, Photocatalytic CO2 conversion experiments)